2,8-Dimesitylboranyl-6H,12H-5,11-methano­dibenzo[b,f][1,5]diazo­cine

In the title compound, C(51)H(56)B(2)N(2), a substituted Tröger’s base, the dihedral angle between the two benzene rings constituting the Tröger’s base framework is 104.42 (6)°. The crystal structure is stabilized by C—H⋯π and weak C—H⋯N inter­actions.

Detalles Bibliográficos
Autor principal: Yuan, Chun-Xue
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254362/
https://www.ncbi.nlm.nih.gov/pubmed/22259501
http://dx.doi.org/10.1107/S1600536811051051
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author Yuan, Chun-Xue
author_facet Yuan, Chun-Xue
author_sort Yuan, Chun-Xue
collection PubMed
description In the title compound, C(51)H(56)B(2)N(2), a substituted Tröger’s base, the dihedral angle between the two benzene rings constituting the Tröger’s base framework is 104.42 (6)°. The crystal structure is stabilized by C—H⋯π and weak C—H⋯N inter­actions.
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spelling pubmed-32543622012-01-18 2,8-Dimesitylboranyl-6H,12H-5,11-methano­dibenzo[b,f][1,5]diazo­cine Yuan, Chun-Xue Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(51)H(56)B(2)N(2), a substituted Tröger’s base, the dihedral angle between the two benzene rings constituting the Tröger’s base framework is 104.42 (6)°. The crystal structure is stabilized by C—H⋯π and weak C—H⋯N inter­actions. International Union of Crystallography 2011-12-03 /pmc/articles/PMC3254362/ /pubmed/22259501 http://dx.doi.org/10.1107/S1600536811051051 Text en © Chun-Xue Yuan 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Yuan, Chun-Xue
2,8-Dimesitylboranyl-6H,12H-5,11-methano­dibenzo[b,f][1,5]diazo­cine
title 2,8-Dimesitylboranyl-6H,12H-5,11-methano­dibenzo[b,f][1,5]diazo­cine
title_full 2,8-Dimesitylboranyl-6H,12H-5,11-methano­dibenzo[b,f][1,5]diazo­cine
title_fullStr 2,8-Dimesitylboranyl-6H,12H-5,11-methano­dibenzo[b,f][1,5]diazo­cine
title_full_unstemmed 2,8-Dimesitylboranyl-6H,12H-5,11-methano­dibenzo[b,f][1,5]diazo­cine
title_short 2,8-Dimesitylboranyl-6H,12H-5,11-methano­dibenzo[b,f][1,5]diazo­cine
title_sort 2,8-dimesitylboranyl-6h,12h-5,11-methano­dibenzo[b,f][1,5]diazo­cine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254362/
https://www.ncbi.nlm.nih.gov/pubmed/22259501
http://dx.doi.org/10.1107/S1600536811051051
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