(1H-Benzimidazol-2-yl)methanaminium perchlorate–18-crown-6–water (1/1/1)

The crystal structure of the title compound C(8)H(10)N(3) (+)·ClO(4) (−)·C(12)H(24)O(6)·H(2)O, consists of an organic (1H-benzimidazol-2-yl)methanaminium cation, an inorganic ClO(4) (−) anion, one 18-crown-6 mol­ecule and one water mol­ecule. In the crystal, the cations and 18-crown-6 mol­ecules are...

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Detalles Bibliográficos
Autor principal: Sun, Su-Wen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254365/
https://www.ncbi.nlm.nih.gov/pubmed/22259530
http://dx.doi.org/10.1107/S1600536811050665
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author Sun, Su-Wen
author_facet Sun, Su-Wen
author_sort Sun, Su-Wen
collection PubMed
description The crystal structure of the title compound C(8)H(10)N(3) (+)·ClO(4) (−)·C(12)H(24)O(6)·H(2)O, consists of an organic (1H-benzimidazol-2-yl)methanaminium cation, an inorganic ClO(4) (−) anion, one 18-crown-6 mol­ecule and one water mol­ecule. In the crystal, the cations and 18-crown-6 mol­ecules are linked by N—H⋯O hydrogen bonds. The crystal packing is stabilized by inter­molecular O—H⋯O, O—H⋯N and O—H⋯Cl hydrogen bonds between anions and the water mol­ecules. One 18-crown-6 C atom and a perchlorate O atom are disordered; both have an occupancy factor ratio of 0.60 (2) and 0.40 (2).
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spelling pubmed-32543652012-01-18 (1H-Benzimidazol-2-yl)methanaminium perchlorate–18-crown-6–water (1/1/1) Sun, Su-Wen Acta Crystallogr Sect E Struct Rep Online Organic Papers The crystal structure of the title compound C(8)H(10)N(3) (+)·ClO(4) (−)·C(12)H(24)O(6)·H(2)O, consists of an organic (1H-benzimidazol-2-yl)methanaminium cation, an inorganic ClO(4) (−) anion, one 18-crown-6 mol­ecule and one water mol­ecule. In the crystal, the cations and 18-crown-6 mol­ecules are linked by N—H⋯O hydrogen bonds. The crystal packing is stabilized by inter­molecular O—H⋯O, O—H⋯N and O—H⋯Cl hydrogen bonds between anions and the water mol­ecules. One 18-crown-6 C atom and a perchlorate O atom are disordered; both have an occupancy factor ratio of 0.60 (2) and 0.40 (2). International Union of Crystallography 2011-12-03 /pmc/articles/PMC3254365/ /pubmed/22259530 http://dx.doi.org/10.1107/S1600536811050665 Text en © Su-Wen Sun 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sun, Su-Wen
(1H-Benzimidazol-2-yl)methanaminium perchlorate–18-crown-6–water (1/1/1)
title (1H-Benzimidazol-2-yl)methanaminium perchlorate–18-crown-6–water (1/1/1)
title_full (1H-Benzimidazol-2-yl)methanaminium perchlorate–18-crown-6–water (1/1/1)
title_fullStr (1H-Benzimidazol-2-yl)methanaminium perchlorate–18-crown-6–water (1/1/1)
title_full_unstemmed (1H-Benzimidazol-2-yl)methanaminium perchlorate–18-crown-6–water (1/1/1)
title_short (1H-Benzimidazol-2-yl)methanaminium perchlorate–18-crown-6–water (1/1/1)
title_sort (1h-benzimidazol-2-yl)methanaminium perchlorate–18-crown-6–water (1/1/1)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254365/
https://www.ncbi.nlm.nih.gov/pubmed/22259530
http://dx.doi.org/10.1107/S1600536811050665
work_keys_str_mv AT sunsuwen 1hbenzimidazol2ylmethanaminiumperchlorate18crown6water111

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