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(2,4,6-Trimethylphenyl)boronic acid–triphenylphosphine oxide (1/1)
In the crystal structure of the title compound, C(9)H(13)BO(2)·C(18)H(15)OP, there are O—H⋯O hydrogen bonds between the O atom of triphenylphosphine oxide and one hydroxy group of the boronic acid. Boronic acid molecules form inversion-related hydrogen-bonded dimers in an R (2) (2)(8) motif. The...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254394/ https://www.ncbi.nlm.nih.gov/pubmed/22259536 http://dx.doi.org/10.1107/S1600536811051609 |
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author | Roşca, Sorin Olaru, Marian Raţ, Ciprian I. |
author_facet | Roşca, Sorin Olaru, Marian Raţ, Ciprian I. |
author_sort | Roşca, Sorin |
collection | PubMed |
description | In the crystal structure of the title compound, C(9)H(13)BO(2)·C(18)H(15)OP, there are O—H⋯O hydrogen bonds between the O atom of triphenylphosphine oxide and one hydroxy group of the boronic acid. Boronic acid molecules form inversion-related hydrogen-bonded dimers in an R (2) (2)(8) motif. The structure is consolidated by intermolecular C—H⋯O bonds and C—H⋯π interactions. |
format | Online Article Text |
id | pubmed-3254394 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32543942012-01-18 (2,4,6-Trimethylphenyl)boronic acid–triphenylphosphine oxide (1/1) Roşca, Sorin Olaru, Marian Raţ, Ciprian I. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, C(9)H(13)BO(2)·C(18)H(15)OP, there are O—H⋯O hydrogen bonds between the O atom of triphenylphosphine oxide and one hydroxy group of the boronic acid. Boronic acid molecules form inversion-related hydrogen-bonded dimers in an R (2) (2)(8) motif. The structure is consolidated by intermolecular C—H⋯O bonds and C—H⋯π interactions. International Union of Crystallography 2011-12-07 /pmc/articles/PMC3254394/ /pubmed/22259536 http://dx.doi.org/10.1107/S1600536811051609 Text en © Roşca et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Roşca, Sorin Olaru, Marian Raţ, Ciprian I. (2,4,6-Trimethylphenyl)boronic acid–triphenylphosphine oxide (1/1) |
title | (2,4,6-Trimethylphenyl)boronic acid–triphenylphosphine oxide (1/1) |
title_full | (2,4,6-Trimethylphenyl)boronic acid–triphenylphosphine oxide (1/1) |
title_fullStr | (2,4,6-Trimethylphenyl)boronic acid–triphenylphosphine oxide (1/1) |
title_full_unstemmed | (2,4,6-Trimethylphenyl)boronic acid–triphenylphosphine oxide (1/1) |
title_short | (2,4,6-Trimethylphenyl)boronic acid–triphenylphosphine oxide (1/1) |
title_sort | (2,4,6-trimethylphenyl)boronic acid–triphenylphosphine oxide (1/1) |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254394/ https://www.ncbi.nlm.nih.gov/pubmed/22259536 http://dx.doi.org/10.1107/S1600536811051609 |
work_keys_str_mv | AT roscasorin 246trimethylphenylboronicacidtriphenylphosphineoxide11 AT olarumarian 246trimethylphenylboronicacidtriphenylphosphineoxide11 AT ratcipriani 246trimethylphenylboronicacidtriphenylphosphineoxide11 |