Cargando…

Kallolide A acetate pyrazoline

In the crystal structure of kallolide A acetate pyrazoline [systematic name: 7-methyl-16-oxo-4,10-bis­(prop-1-en-2-yl)-17,18-dioxa-14,15-diaza­tetra­cyclo­[9.4.2.1(6,9).0(1,12)]octa­deca-6,8,14-trien-5-yl acetate], C(23)H(28)N(2)O(5), there is a 12-member­ed carbon macrocyclic structure. In addition...

Descripción completa

Detalles Bibliográficos
Autores principales: Rodríguez-Escudero, Idaliz, Marrero, Jeffrey, Rodríguez, Abimael D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254402/
https://www.ncbi.nlm.nih.gov/pubmed/22259545
http://dx.doi.org/10.1107/S1600536811051890
Descripción
Sumario:In the crystal structure of kallolide A acetate pyrazoline [systematic name: 7-methyl-16-oxo-4,10-bis­(prop-1-en-2-yl)-17,18-dioxa-14,15-diaza­tetra­cyclo­[9.4.2.1(6,9).0(1,12)]octa­deca-6,8,14-trien-5-yl acetate], C(23)H(28)N(2)O(5), there is a 12-member­ed carbon macrocyclic structure. In addition, there is a tris­ubstituted furan ring, an approximately planar γ-lactone ring [maximum deviation of 0.057 (3) Å] and a pyraz­oline ring, the latter in an envelope conformation. The pyrazoline and the γ-lactone rings are fused in a cis configuration. In the crystal, mol­ecules are linked by weak C—H⋯O inter­actions, forming a two-dimensional network parallel to (001). An intra­molecular C—H⋯O hydrogen bond is also present.