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trans-(Ethene-1,2-diyl)bis(diphenylphosphine selenide)
In the title molecule, C(26)H(22)P(2)Se(2), both P atoms have distorted tetrahedral environments, resulting in effective cone angles of 177 and 174°. Inversion twinning was detected and refined to a ratio of 0.35:0.65. Weak intermolecular C—H⋯Se interactions are observed.
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254404/ https://www.ncbi.nlm.nih.gov/pubmed/22259547 http://dx.doi.org/10.1107/S160053681105183X |
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author | Phasha, Zanele Makhoba, Sizwe Muller, Alfred |
author_facet | Phasha, Zanele Makhoba, Sizwe Muller, Alfred |
author_sort | Phasha, Zanele |
collection | PubMed |
description | In the title molecule, C(26)H(22)P(2)Se(2), both P atoms have distorted tetrahedral environments, resulting in effective cone angles of 177 and 174°. Inversion twinning was detected and refined to a ratio of 0.35:0.65. Weak intermolecular C—H⋯Se interactions are observed. |
format | Online Article Text |
id | pubmed-3254404 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32544042012-01-18 trans-(Ethene-1,2-diyl)bis(diphenylphosphine selenide) Phasha, Zanele Makhoba, Sizwe Muller, Alfred Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title molecule, C(26)H(22)P(2)Se(2), both P atoms have distorted tetrahedral environments, resulting in effective cone angles of 177 and 174°. Inversion twinning was detected and refined to a ratio of 0.35:0.65. Weak intermolecular C—H⋯Se interactions are observed. International Union of Crystallography 2011-12-07 /pmc/articles/PMC3254404/ /pubmed/22259547 http://dx.doi.org/10.1107/S160053681105183X Text en © Phasha et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Phasha, Zanele Makhoba, Sizwe Muller, Alfred trans-(Ethene-1,2-diyl)bis(diphenylphosphine selenide) |
title |
trans-(Ethene-1,2-diyl)bis(diphenylphosphine selenide) |
title_full |
trans-(Ethene-1,2-diyl)bis(diphenylphosphine selenide) |
title_fullStr |
trans-(Ethene-1,2-diyl)bis(diphenylphosphine selenide) |
title_full_unstemmed |
trans-(Ethene-1,2-diyl)bis(diphenylphosphine selenide) |
title_short |
trans-(Ethene-1,2-diyl)bis(diphenylphosphine selenide) |
title_sort | trans-(ethene-1,2-diyl)bis(diphenylphosphine selenide) |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254404/ https://www.ncbi.nlm.nih.gov/pubmed/22259547 http://dx.doi.org/10.1107/S160053681105183X |
work_keys_str_mv | AT phashazanele transethene12diylbisdiphenylphosphineselenide AT makhobasizwe transethene12diylbisdiphenylphosphineselenide AT mulleralfred transethene12diylbisdiphenylphosphineselenide |