Cargando…

trans-(Ethene-1,2-di­yl)bis­(diphenyl­phosphine selenide)

In the title mol­ecule, C(26)H(22)P(2)Se(2), both P atoms have distorted tetra­hedral environments, resulting in effective cone angles of 177 and 174°. Inversion twinning was detected and refined to a ratio of 0.35:0.65. Weak inter­molecular C—H⋯Se inter­actions are observed.

Detalles Bibliográficos
Autores principales: Phasha, Zanele, Makhoba, Sizwe, Muller, Alfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254404/
https://www.ncbi.nlm.nih.gov/pubmed/22259547
http://dx.doi.org/10.1107/S160053681105183X
_version_ 1782220846405779456
author Phasha, Zanele
Makhoba, Sizwe
Muller, Alfred
author_facet Phasha, Zanele
Makhoba, Sizwe
Muller, Alfred
author_sort Phasha, Zanele
collection PubMed
description In the title mol­ecule, C(26)H(22)P(2)Se(2), both P atoms have distorted tetra­hedral environments, resulting in effective cone angles of 177 and 174°. Inversion twinning was detected and refined to a ratio of 0.35:0.65. Weak inter­molecular C—H⋯Se inter­actions are observed.
format Online
Article
Text
id pubmed-3254404
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32544042012-01-18 trans-(Ethene-1,2-di­yl)bis­(diphenyl­phosphine selenide) Phasha, Zanele Makhoba, Sizwe Muller, Alfred Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(26)H(22)P(2)Se(2), both P atoms have distorted tetra­hedral environments, resulting in effective cone angles of 177 and 174°. Inversion twinning was detected and refined to a ratio of 0.35:0.65. Weak inter­molecular C—H⋯Se inter­actions are observed. International Union of Crystallography 2011-12-07 /pmc/articles/PMC3254404/ /pubmed/22259547 http://dx.doi.org/10.1107/S160053681105183X Text en © Phasha et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Phasha, Zanele
Makhoba, Sizwe
Muller, Alfred
trans-(Ethene-1,2-di­yl)bis­(diphenyl­phosphine selenide)
title trans-(Ethene-1,2-di­yl)bis­(diphenyl­phosphine selenide)
title_full trans-(Ethene-1,2-di­yl)bis­(diphenyl­phosphine selenide)
title_fullStr trans-(Ethene-1,2-di­yl)bis­(diphenyl­phosphine selenide)
title_full_unstemmed trans-(Ethene-1,2-di­yl)bis­(diphenyl­phosphine selenide)
title_short trans-(Ethene-1,2-di­yl)bis­(diphenyl­phosphine selenide)
title_sort trans-(ethene-1,2-di­yl)bis­(diphenyl­phosphine selenide)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254404/
https://www.ncbi.nlm.nih.gov/pubmed/22259547
http://dx.doi.org/10.1107/S160053681105183X
work_keys_str_mv AT phashazanele transethene12diylbisdiphenylphosphineselenide
AT makhobasizwe transethene12diylbisdiphenylphosphineselenide
AT mulleralfred transethene12diylbisdiphenylphosphineselenide