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2,5-Bis(1,3-dithiol-2-ylidene)-1,3-dithiolane-4-thione
The asymmetric unit of the title compound, C(9)H(4)S(7), contains two independent molecules, in one of which the central five-membered ring is disordered over two orientations in a 0.924 (3):0.076 (3) ratio. The molecular skeleton is almost planar: the average distance of the atoms from their mean...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254410/ https://www.ncbi.nlm.nih.gov/pubmed/22259554 http://dx.doi.org/10.1107/S1600536811051518 |
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author | Ueda, Kazumasa Suzuki, Kenta Kunimoto, Kei Yoza, Kenji |
author_facet | Ueda, Kazumasa Suzuki, Kenta Kunimoto, Kei Yoza, Kenji |
author_sort | Ueda, Kazumasa |
collection | PubMed |
description | The asymmetric unit of the title compound, C(9)H(4)S(7), contains two independent molecules, in one of which the central five-membered ring is disordered over two orientations in a 0.924 (3):0.076 (3) ratio. The molecular skeleton is almost planar: the average distance of the atoms from their mean plane is 0.128 (7) Å in the ordered molecule, and 0.088 (5) and 0.123 (2) Å in the major and minor disorder components, respectively. The ordered and disordered molecules form separate columns by stacking along the b axis. Adjacent columns interact via short S⋯S [3.33 (2), 3.434 (3), 3.444 (2), 3.503 (2), 3.519 (3) and 3.53 (4) Å] and S⋯H [2.814 (2), 2.87 (7), 2.92 (2), 2.9269 (18), 2.93 (2), 2.94 (2), 2.939 (2), 2.967 (2) and 2.974 (1) Å] contacts. |
format | Online Article Text |
id | pubmed-3254410 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32544102012-01-18 2,5-Bis(1,3-dithiol-2-ylidene)-1,3-dithiolane-4-thione Ueda, Kazumasa Suzuki, Kenta Kunimoto, Kei Yoza, Kenji Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(9)H(4)S(7), contains two independent molecules, in one of which the central five-membered ring is disordered over two orientations in a 0.924 (3):0.076 (3) ratio. The molecular skeleton is almost planar: the average distance of the atoms from their mean plane is 0.128 (7) Å in the ordered molecule, and 0.088 (5) and 0.123 (2) Å in the major and minor disorder components, respectively. The ordered and disordered molecules form separate columns by stacking along the b axis. Adjacent columns interact via short S⋯S [3.33 (2), 3.434 (3), 3.444 (2), 3.503 (2), 3.519 (3) and 3.53 (4) Å] and S⋯H [2.814 (2), 2.87 (7), 2.92 (2), 2.9269 (18), 2.93 (2), 2.94 (2), 2.939 (2), 2.967 (2) and 2.974 (1) Å] contacts. International Union of Crystallography 2011-12-10 /pmc/articles/PMC3254410/ /pubmed/22259554 http://dx.doi.org/10.1107/S1600536811051518 Text en © Ueda et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Ueda, Kazumasa Suzuki, Kenta Kunimoto, Kei Yoza, Kenji 2,5-Bis(1,3-dithiol-2-ylidene)-1,3-dithiolane-4-thione |
title | 2,5-Bis(1,3-dithiol-2-ylidene)-1,3-dithiolane-4-thione |
title_full | 2,5-Bis(1,3-dithiol-2-ylidene)-1,3-dithiolane-4-thione |
title_fullStr | 2,5-Bis(1,3-dithiol-2-ylidene)-1,3-dithiolane-4-thione |
title_full_unstemmed | 2,5-Bis(1,3-dithiol-2-ylidene)-1,3-dithiolane-4-thione |
title_short | 2,5-Bis(1,3-dithiol-2-ylidene)-1,3-dithiolane-4-thione |
title_sort | 2,5-bis(1,3-dithiol-2-ylidene)-1,3-dithiolane-4-thione |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254410/ https://www.ncbi.nlm.nih.gov/pubmed/22259554 http://dx.doi.org/10.1107/S1600536811051518 |
work_keys_str_mv | AT uedakazumasa 25bis13dithiol2ylidene13dithiolane4thione AT suzukikenta 25bis13dithiol2ylidene13dithiolane4thione AT kunimotokei 25bis13dithiol2ylidene13dithiolane4thione AT yozakenji 25bis13dithiol2ylidene13dithiolane4thione |