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2,5-Bis(1,3-dithiol-2-yl­idene)-1,3-dithiol­ane-4-thione

The asymmetric unit of the title compound, C(9)H(4)S(7), contains two independent mol­ecules, in one of which the central five-membered ring is disordered over two orientations in a 0.924 (3):0.076 (3) ratio. The mol­ecular skeleton is almost planar: the average distance of the atoms from their mean...

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Detalles Bibliográficos
Autores principales: Ueda, Kazumasa, Suzuki, Kenta, Kunimoto, Kei, Yoza, Kenji
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254410/
https://www.ncbi.nlm.nih.gov/pubmed/22259554
http://dx.doi.org/10.1107/S1600536811051518
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author Ueda, Kazumasa
Suzuki, Kenta
Kunimoto, Kei
Yoza, Kenji
author_facet Ueda, Kazumasa
Suzuki, Kenta
Kunimoto, Kei
Yoza, Kenji
author_sort Ueda, Kazumasa
collection PubMed
description The asymmetric unit of the title compound, C(9)H(4)S(7), contains two independent mol­ecules, in one of which the central five-membered ring is disordered over two orientations in a 0.924 (3):0.076 (3) ratio. The mol­ecular skeleton is almost planar: the average distance of the atoms from their mean plane is 0.128 (7) Å in the ordered mol­ecule, and 0.088 (5) and 0.123 (2) Å in the major and minor disorder components, respectively. The ordered and disordered mol­ecules form separate columns by stacking along the b axis. Adjacent columns inter­act via short S⋯S [3.33 (2), 3.434 (3), 3.444 (2), 3.503 (2), 3.519 (3) and 3.53 (4) Å] and S⋯H [2.814 (2), 2.87 (7), 2.92 (2), 2.9269 (18), 2.93 (2), 2.94 (2), 2.939 (2), 2.967 (2) and 2.974 (1) Å] contacts.
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spelling pubmed-32544102012-01-18 2,5-Bis(1,3-dithiol-2-yl­idene)-1,3-dithiol­ane-4-thione Ueda, Kazumasa Suzuki, Kenta Kunimoto, Kei Yoza, Kenji Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(9)H(4)S(7), contains two independent mol­ecules, in one of which the central five-membered ring is disordered over two orientations in a 0.924 (3):0.076 (3) ratio. The mol­ecular skeleton is almost planar: the average distance of the atoms from their mean plane is 0.128 (7) Å in the ordered mol­ecule, and 0.088 (5) and 0.123 (2) Å in the major and minor disorder components, respectively. The ordered and disordered mol­ecules form separate columns by stacking along the b axis. Adjacent columns inter­act via short S⋯S [3.33 (2), 3.434 (3), 3.444 (2), 3.503 (2), 3.519 (3) and 3.53 (4) Å] and S⋯H [2.814 (2), 2.87 (7), 2.92 (2), 2.9269 (18), 2.93 (2), 2.94 (2), 2.939 (2), 2.967 (2) and 2.974 (1) Å] contacts. International Union of Crystallography 2011-12-10 /pmc/articles/PMC3254410/ /pubmed/22259554 http://dx.doi.org/10.1107/S1600536811051518 Text en © Ueda et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ueda, Kazumasa
Suzuki, Kenta
Kunimoto, Kei
Yoza, Kenji
2,5-Bis(1,3-dithiol-2-yl­idene)-1,3-dithiol­ane-4-thione
title 2,5-Bis(1,3-dithiol-2-yl­idene)-1,3-dithiol­ane-4-thione
title_full 2,5-Bis(1,3-dithiol-2-yl­idene)-1,3-dithiol­ane-4-thione
title_fullStr 2,5-Bis(1,3-dithiol-2-yl­idene)-1,3-dithiol­ane-4-thione
title_full_unstemmed 2,5-Bis(1,3-dithiol-2-yl­idene)-1,3-dithiol­ane-4-thione
title_short 2,5-Bis(1,3-dithiol-2-yl­idene)-1,3-dithiol­ane-4-thione
title_sort 2,5-bis(1,3-dithiol-2-yl­idene)-1,3-dithiol­ane-4-thione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254410/
https://www.ncbi.nlm.nih.gov/pubmed/22259554
http://dx.doi.org/10.1107/S1600536811051518
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