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Dihydroallocryptopine
In the title compound [systematic name: 7,8-dimethoxy-11-methyl-17,19-dioxa-11-azatetracyclo[12.7.0.0(4,9).0(16,20)]henicosa-1(21),4,6,8,14,16 (20)-hexaen-2-ol], C(21)H(25)NO(5), the benzene rings are inclined at a dihedral angle of 23.16 (5)°. One of the methoxy C atoms is close to coplanar wi...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254424/ https://www.ncbi.nlm.nih.gov/pubmed/22259569 http://dx.doi.org/10.1107/S1600536811052172 |
Sumario: | In the title compound [systematic name: 7,8-dimethoxy-11-methyl-17,19-dioxa-11-azatetracyclo[12.7.0.0(4,9).0(16,20)]henicosa-1(21),4,6,8,14,16 (20)-hexaen-2-ol], C(21)H(25)NO(5), the benzene rings are inclined at a dihedral angle of 23.16 (5)°. One of the methoxy C atoms is close to coplanar with its attached ring [deviation = 0.129 (3) Å], whereas the other is orientated away from the ring [deviation = −1.124 (2) Å]. The 10-membered ring is highly puckered, and the OH and CH(3) substituents project to the same side of the ring. In the crystal, O—H⋯O hydrogen bonds link the molecules into [010] chains and C—H⋯O and C—H⋯π interactions consolidate the packing. |
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