(Z)-1,1-Dicyano-2-(4-fluoro­phen­yl)-3-(1-hexyl­pyridin-1-ium-4-yl)prop-2-en-1-ide

The title compound, C(22)H(22)FN(3), exists as a zwitterion with the negative charge on the dicyano­methanide group and the positive charge on the pyridinium N atom. The mol­ecule adopts a Z conformation about the central C=C bond. The dihedral angle between the pyridinium and benzene rings is 65.65...

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Detalles Bibliográficos
Autores principales: Hao, Wen-Hui, Wang, Cheng, Qian, Gang, Wang, Zhi-Yuan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254434/
https://www.ncbi.nlm.nih.gov/pubmed/22259581
http://dx.doi.org/10.1107/S160053681105166X
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author Hao, Wen-Hui
Wang, Cheng
Qian, Gang
Wang, Zhi-Yuan
author_facet Hao, Wen-Hui
Wang, Cheng
Qian, Gang
Wang, Zhi-Yuan
author_sort Hao, Wen-Hui
collection PubMed
description The title compound, C(22)H(22)FN(3), exists as a zwitterion with the negative charge on the dicyano­methanide group and the positive charge on the pyridinium N atom. The mol­ecule adopts a Z conformation about the central C=C bond. The dihedral angle between the pyridinium and benzene rings is 65.65 (5)°. Weak C—H⋯N hydrogen bonding is present in the crystal structure.
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spelling pubmed-32544342012-01-18 (Z)-1,1-Dicyano-2-(4-fluoro­phen­yl)-3-(1-hexyl­pyridin-1-ium-4-yl)prop-2-en-1-ide Hao, Wen-Hui Wang, Cheng Qian, Gang Wang, Zhi-Yuan Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(22)H(22)FN(3), exists as a zwitterion with the negative charge on the dicyano­methanide group and the positive charge on the pyridinium N atom. The mol­ecule adopts a Z conformation about the central C=C bond. The dihedral angle between the pyridinium and benzene rings is 65.65 (5)°. Weak C—H⋯N hydrogen bonding is present in the crystal structure. International Union of Crystallography 2011-12-10 /pmc/articles/PMC3254434/ /pubmed/22259581 http://dx.doi.org/10.1107/S160053681105166X Text en © Hao et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Hao, Wen-Hui
Wang, Cheng
Qian, Gang
Wang, Zhi-Yuan
(Z)-1,1-Dicyano-2-(4-fluoro­phen­yl)-3-(1-hexyl­pyridin-1-ium-4-yl)prop-2-en-1-ide
title (Z)-1,1-Dicyano-2-(4-fluoro­phen­yl)-3-(1-hexyl­pyridin-1-ium-4-yl)prop-2-en-1-ide
title_full (Z)-1,1-Dicyano-2-(4-fluoro­phen­yl)-3-(1-hexyl­pyridin-1-ium-4-yl)prop-2-en-1-ide
title_fullStr (Z)-1,1-Dicyano-2-(4-fluoro­phen­yl)-3-(1-hexyl­pyridin-1-ium-4-yl)prop-2-en-1-ide
title_full_unstemmed (Z)-1,1-Dicyano-2-(4-fluoro­phen­yl)-3-(1-hexyl­pyridin-1-ium-4-yl)prop-2-en-1-ide
title_short (Z)-1,1-Dicyano-2-(4-fluoro­phen­yl)-3-(1-hexyl­pyridin-1-ium-4-yl)prop-2-en-1-ide
title_sort (z)-1,1-dicyano-2-(4-fluoro­phen­yl)-3-(1-hexyl­pyridin-1-ium-4-yl)prop-2-en-1-ide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254434/
https://www.ncbi.nlm.nih.gov/pubmed/22259581
http://dx.doi.org/10.1107/S160053681105166X
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