(E)-2-[(1-Benzyl­piperidin-4-yl)imino­meth­yl]phenol

There are two mol­ecules in the asymmetric unit of the title compound, C(19)H(22)N(2)O. Both mol­ecules have an E conformation about their C=N bonds and both piperdine rings adopt chair conformations with their N atoms adopting pyramidal geometries [bond angle sums = 329.8 (4) and 330.2 (4)°]. Both...

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Detalles Bibliográficos
Autores principales: Fang, Rui-Qin, Xiao, Zhu-Ping, Zuo, Yun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254437/
https://www.ncbi.nlm.nih.gov/pubmed/22259584
http://dx.doi.org/10.1107/S160053681105197X
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author Fang, Rui-Qin
Xiao, Zhu-Ping
Zuo, Yun
author_facet Fang, Rui-Qin
Xiao, Zhu-Ping
Zuo, Yun
author_sort Fang, Rui-Qin
collection PubMed
description There are two mol­ecules in the asymmetric unit of the title compound, C(19)H(22)N(2)O. Both mol­ecules have an E conformation about their C=N bonds and both piperdine rings adopt chair conformations with their N atoms adopting pyramidal geometries [bond angle sums = 329.8 (4) and 330.2 (4)°]. Both mol­ecules feature an intra­molecular O—H⋯N hydrogen bond, which generates an S(6) ring. The dihedral angles between the phenyl and benzene ring planes are 45.97 (18) and 66.0 (2)°. Short O—H⋯O contacts occur in the crystal.
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spelling pubmed-32544372012-01-18 (E)-2-[(1-Benzyl­piperidin-4-yl)imino­meth­yl]phenol Fang, Rui-Qin Xiao, Zhu-Ping Zuo, Yun Acta Crystallogr Sect E Struct Rep Online Organic Papers There are two mol­ecules in the asymmetric unit of the title compound, C(19)H(22)N(2)O. Both mol­ecules have an E conformation about their C=N bonds and both piperdine rings adopt chair conformations with their N atoms adopting pyramidal geometries [bond angle sums = 329.8 (4) and 330.2 (4)°]. Both mol­ecules feature an intra­molecular O—H⋯N hydrogen bond, which generates an S(6) ring. The dihedral angles between the phenyl and benzene ring planes are 45.97 (18) and 66.0 (2)°. Short O—H⋯O contacts occur in the crystal. International Union of Crystallography 2011-12-10 /pmc/articles/PMC3254437/ /pubmed/22259584 http://dx.doi.org/10.1107/S160053681105197X Text en © Fang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fang, Rui-Qin
Xiao, Zhu-Ping
Zuo, Yun
(E)-2-[(1-Benzyl­piperidin-4-yl)imino­meth­yl]phenol
title (E)-2-[(1-Benzyl­piperidin-4-yl)imino­meth­yl]phenol
title_full (E)-2-[(1-Benzyl­piperidin-4-yl)imino­meth­yl]phenol
title_fullStr (E)-2-[(1-Benzyl­piperidin-4-yl)imino­meth­yl]phenol
title_full_unstemmed (E)-2-[(1-Benzyl­piperidin-4-yl)imino­meth­yl]phenol
title_short (E)-2-[(1-Benzyl­piperidin-4-yl)imino­meth­yl]phenol
title_sort (e)-2-[(1-benzyl­piperidin-4-yl)imino­meth­yl]phenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254437/
https://www.ncbi.nlm.nih.gov/pubmed/22259584
http://dx.doi.org/10.1107/S160053681105197X
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