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2-(3-Benzoyl-4-hydroxy-1,1-dioxo-2H-1λ(6),2-benzothiazin-2-yl)-1-phenylethanone
In the title molecule, C(23)H(17)NO(5)S, the heterocyclic thiazine ring adopts a half-chair conformation, with the S and N atoms displaced by 0.383 (3) and 0.473 (3) Å, respectively, on opposite sides of the mean plane formed by the ring C atoms. The phenyl rings attached to carbonyl groups lie al...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254443/ https://www.ncbi.nlm.nih.gov/pubmed/22259591 http://dx.doi.org/10.1107/S1600536811052615 |
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author | Sattar, Nazia Siddiqui, Hamid Latif Bukhari, Syed Iftikhar Hussain Ahmad, Matloob Parvez, Masood |
author_facet | Sattar, Nazia Siddiqui, Hamid Latif Bukhari, Syed Iftikhar Hussain Ahmad, Matloob Parvez, Masood |
author_sort | Sattar, Nazia |
collection | PubMed |
description | In the title molecule, C(23)H(17)NO(5)S, the heterocyclic thiazine ring adopts a half-chair conformation, with the S and N atoms displaced by 0.383 (3) and 0.473 (3) Å, respectively, on opposite sides of the mean plane formed by the ring C atoms. The phenyl rings attached to carbonyl groups lie almost parallel to each other at a dihedral angle 7.43 (9)°, the distance between the centroids of the rings being 3.780 (1) Å. The C(thiazine)—C=O and O=C—CH(2) groups make dihedral angles of 37.56 (16) and 1.93 (18)°, respectively, with the phenyl groups to which they are attached. The crystal structure features O—H⋯O and C—H⋯O hydrogen bonds and further consolidated by C—H⋯π interactions; an intramolecular O—H⋯O hydrogen bond is also present. |
format | Online Article Text |
id | pubmed-3254443 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32544432012-01-18 2-(3-Benzoyl-4-hydroxy-1,1-dioxo-2H-1λ(6),2-benzothiazin-2-yl)-1-phenylethanone Sattar, Nazia Siddiqui, Hamid Latif Bukhari, Syed Iftikhar Hussain Ahmad, Matloob Parvez, Masood Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title molecule, C(23)H(17)NO(5)S, the heterocyclic thiazine ring adopts a half-chair conformation, with the S and N atoms displaced by 0.383 (3) and 0.473 (3) Å, respectively, on opposite sides of the mean plane formed by the ring C atoms. The phenyl rings attached to carbonyl groups lie almost parallel to each other at a dihedral angle 7.43 (9)°, the distance between the centroids of the rings being 3.780 (1) Å. The C(thiazine)—C=O and O=C—CH(2) groups make dihedral angles of 37.56 (16) and 1.93 (18)°, respectively, with the phenyl groups to which they are attached. The crystal structure features O—H⋯O and C—H⋯O hydrogen bonds and further consolidated by C—H⋯π interactions; an intramolecular O—H⋯O hydrogen bond is also present. International Union of Crystallography 2011-12-10 /pmc/articles/PMC3254443/ /pubmed/22259591 http://dx.doi.org/10.1107/S1600536811052615 Text en © Sattar et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Sattar, Nazia Siddiqui, Hamid Latif Bukhari, Syed Iftikhar Hussain Ahmad, Matloob Parvez, Masood 2-(3-Benzoyl-4-hydroxy-1,1-dioxo-2H-1λ(6),2-benzothiazin-2-yl)-1-phenylethanone |
title | 2-(3-Benzoyl-4-hydroxy-1,1-dioxo-2H-1λ(6),2-benzothiazin-2-yl)-1-phenylethanone |
title_full | 2-(3-Benzoyl-4-hydroxy-1,1-dioxo-2H-1λ(6),2-benzothiazin-2-yl)-1-phenylethanone |
title_fullStr | 2-(3-Benzoyl-4-hydroxy-1,1-dioxo-2H-1λ(6),2-benzothiazin-2-yl)-1-phenylethanone |
title_full_unstemmed | 2-(3-Benzoyl-4-hydroxy-1,1-dioxo-2H-1λ(6),2-benzothiazin-2-yl)-1-phenylethanone |
title_short | 2-(3-Benzoyl-4-hydroxy-1,1-dioxo-2H-1λ(6),2-benzothiazin-2-yl)-1-phenylethanone |
title_sort | 2-(3-benzoyl-4-hydroxy-1,1-dioxo-2h-1λ(6),2-benzothiazin-2-yl)-1-phenylethanone |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254443/ https://www.ncbi.nlm.nih.gov/pubmed/22259591 http://dx.doi.org/10.1107/S1600536811052615 |
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