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2-(5-Fluoro-2,3-dioxoindolin-1-yl)ethyl 4-methylpiperazine-1-carbodithioate
In the title compound, C(16)H(18)FN(3)O(2)S(2), the methylpiperazine ring adopts a chair conformation, while the (2,3-dioxoindolin-1-yl)ethyl unit is linked to one of the N atoms of the piperazine ring via the carbodithioate group. In the crystal, each molecule is linked to its neighbors within t...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254445/ https://www.ncbi.nlm.nih.gov/pubmed/22259593 http://dx.doi.org/10.1107/S1600536811052494 |
Sumario: | In the title compound, C(16)H(18)FN(3)O(2)S(2), the methylpiperazine ring adopts a chair conformation, while the (2,3-dioxoindolin-1-yl)ethyl unit is linked to one of the N atoms of the piperazine ring via the carbodithioate group. In the crystal, each molecule is linked to its neighbors within the ([Image: see text]03) plane through weak C—H(methylene)⋯O, C—H(aryl)⋯O and C—H(methylene)⋯S interactions. Perpendicular to this plane molecules are connected through intermolecular short N⋯π(pyrrole ring) contacts [N⋯C centroid = 3.232 (2) Å], another set of C—H(methylene)⋯O interactions and through short contacts between carbodithioate S atoms and the pyrrole rings [C⋯centroid = 3.695 (3), S⋯centroid = 3.403 (2) Å]. |
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