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2-(5-Fluoro-2,3-dioxoindolin-1-yl)ethyl 4-methyl­piperazine-1-carbodithio­ate

In the title compound, C(16)H(18)FN(3)O(2)S(2), the methyl­piperazine ring adopts a chair conformation, while the (2,3-dioxoindolin-1-yl)ethyl unit is linked to one of the N atoms of the piperazine ring via the carbodithio­ate group. In the crystal, each mol­ecule is linked to its neighbors within t...

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Detalles Bibliográficos
Autores principales: Wang, Yao, Lin, Hui-Hui, Cao, Sheng-Li
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254445/
https://www.ncbi.nlm.nih.gov/pubmed/22259593
http://dx.doi.org/10.1107/S1600536811052494
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author Wang, Yao
Lin, Hui-Hui
Cao, Sheng-Li
author_facet Wang, Yao
Lin, Hui-Hui
Cao, Sheng-Li
author_sort Wang, Yao
collection PubMed
description In the title compound, C(16)H(18)FN(3)O(2)S(2), the methyl­piperazine ring adopts a chair conformation, while the (2,3-dioxoindolin-1-yl)ethyl unit is linked to one of the N atoms of the piperazine ring via the carbodithio­ate group. In the crystal, each mol­ecule is linked to its neighbors within the ([Image: see text]03) plane through weak C—H(methyl­ene)⋯O, C—H(ar­yl)⋯O and C—H(methyl­ene)⋯S inter­actions. Perpendicular to this plane mol­ecules are connected through inter­molecular short N⋯π(pyrrole ring) contacts [N⋯C centroid = 3.232 (2) Å], another set of C—H(methyl­ene)⋯O inter­actions and through short contacts between carbodithio­ate S atoms and the pyrrole rings [C⋯centroid = 3.695 (3), S⋯centroid = 3.403 (2) Å].
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spelling pubmed-32544452012-01-18 2-(5-Fluoro-2,3-dioxoindolin-1-yl)ethyl 4-methyl­piperazine-1-carbodithio­ate Wang, Yao Lin, Hui-Hui Cao, Sheng-Li Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(18)FN(3)O(2)S(2), the methyl­piperazine ring adopts a chair conformation, while the (2,3-dioxoindolin-1-yl)ethyl unit is linked to one of the N atoms of the piperazine ring via the carbodithio­ate group. In the crystal, each mol­ecule is linked to its neighbors within the ([Image: see text]03) plane through weak C—H(methyl­ene)⋯O, C—H(ar­yl)⋯O and C—H(methyl­ene)⋯S inter­actions. Perpendicular to this plane mol­ecules are connected through inter­molecular short N⋯π(pyrrole ring) contacts [N⋯C centroid = 3.232 (2) Å], another set of C—H(methyl­ene)⋯O inter­actions and through short contacts between carbodithio­ate S atoms and the pyrrole rings [C⋯centroid = 3.695 (3), S⋯centroid = 3.403 (2) Å]. International Union of Crystallography 2011-12-10 /pmc/articles/PMC3254445/ /pubmed/22259593 http://dx.doi.org/10.1107/S1600536811052494 Text en © Wang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Wang, Yao
Lin, Hui-Hui
Cao, Sheng-Li
2-(5-Fluoro-2,3-dioxoindolin-1-yl)ethyl 4-methyl­piperazine-1-carbodithio­ate
title 2-(5-Fluoro-2,3-dioxoindolin-1-yl)ethyl 4-methyl­piperazine-1-carbodithio­ate
title_full 2-(5-Fluoro-2,3-dioxoindolin-1-yl)ethyl 4-methyl­piperazine-1-carbodithio­ate
title_fullStr 2-(5-Fluoro-2,3-dioxoindolin-1-yl)ethyl 4-methyl­piperazine-1-carbodithio­ate
title_full_unstemmed 2-(5-Fluoro-2,3-dioxoindolin-1-yl)ethyl 4-methyl­piperazine-1-carbodithio­ate
title_short 2-(5-Fluoro-2,3-dioxoindolin-1-yl)ethyl 4-methyl­piperazine-1-carbodithio­ate
title_sort 2-(5-fluoro-2,3-dioxoindolin-1-yl)ethyl 4-methyl­piperazine-1-carbodithio­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254445/
https://www.ncbi.nlm.nih.gov/pubmed/22259593
http://dx.doi.org/10.1107/S1600536811052494
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