3-(4-Fluoro­phenyl­sulfon­yl)-5-iodo-2,7-dimethyl-1-benzofuran

In the title compound, C(16)H(12)FIO(3)S, the 4-fluoro­phenyl ring makes a dihedral angle of 72.31 (6)° with the mean plane of the benzofuran fragment. In the crystal, mol­ecules are linked by weak C—H⋯O hydrogen bonds, and by an I⋯I contact [3.7764 (3) Å]. The crystal structure also exhibits a weak...

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Detalles Bibliográficos
Autores principales: Seo, Pil Ja, Choi, Hong Dae, Son, Byeng Wha, Lee, Uk
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254446/
https://www.ncbi.nlm.nih.gov/pubmed/22259594
http://dx.doi.org/10.1107/S1600536811052792
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author Seo, Pil Ja
Choi, Hong Dae
Son, Byeng Wha
Lee, Uk
author_facet Seo, Pil Ja
Choi, Hong Dae
Son, Byeng Wha
Lee, Uk
author_sort Seo, Pil Ja
collection PubMed
description In the title compound, C(16)H(12)FIO(3)S, the 4-fluoro­phenyl ring makes a dihedral angle of 72.31 (6)° with the mean plane of the benzofuran fragment. In the crystal, mol­ecules are linked by weak C—H⋯O hydrogen bonds, and by an I⋯I contact [3.7764 (3) Å]. The crystal structure also exhibits a weak C—I⋯π [3.901 (3) Å] inter­action and a slipped π–π inter­action between the furan and benzene rings of neighbouring mol­ecules [centroid–centroid distance = 3.845 (3), inter­planar distance = 3.555 (3) and slippage = 1.465 (3) Å].
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spelling pubmed-32544462012-01-18 3-(4-Fluoro­phenyl­sulfon­yl)-5-iodo-2,7-dimethyl-1-benzofuran Seo, Pil Ja Choi, Hong Dae Son, Byeng Wha Lee, Uk Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(12)FIO(3)S, the 4-fluoro­phenyl ring makes a dihedral angle of 72.31 (6)° with the mean plane of the benzofuran fragment. In the crystal, mol­ecules are linked by weak C—H⋯O hydrogen bonds, and by an I⋯I contact [3.7764 (3) Å]. The crystal structure also exhibits a weak C—I⋯π [3.901 (3) Å] inter­action and a slipped π–π inter­action between the furan and benzene rings of neighbouring mol­ecules [centroid–centroid distance = 3.845 (3), inter­planar distance = 3.555 (3) and slippage = 1.465 (3) Å]. International Union of Crystallography 2011-12-10 /pmc/articles/PMC3254446/ /pubmed/22259594 http://dx.doi.org/10.1107/S1600536811052792 Text en © Seo et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Seo, Pil Ja
Choi, Hong Dae
Son, Byeng Wha
Lee, Uk
3-(4-Fluoro­phenyl­sulfon­yl)-5-iodo-2,7-dimethyl-1-benzofuran
title 3-(4-Fluoro­phenyl­sulfon­yl)-5-iodo-2,7-dimethyl-1-benzofuran
title_full 3-(4-Fluoro­phenyl­sulfon­yl)-5-iodo-2,7-dimethyl-1-benzofuran
title_fullStr 3-(4-Fluoro­phenyl­sulfon­yl)-5-iodo-2,7-dimethyl-1-benzofuran
title_full_unstemmed 3-(4-Fluoro­phenyl­sulfon­yl)-5-iodo-2,7-dimethyl-1-benzofuran
title_short 3-(4-Fluoro­phenyl­sulfon­yl)-5-iodo-2,7-dimethyl-1-benzofuran
title_sort 3-(4-fluoro­phenyl­sulfon­yl)-5-iodo-2,7-dimethyl-1-benzofuran
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254446/
https://www.ncbi.nlm.nih.gov/pubmed/22259594
http://dx.doi.org/10.1107/S1600536811052792
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AT leeuk 34fluorophenylsulfonyl5iodo27dimethyl1benzofuran

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