3,14-Dimethyl-2,6,13,17-tetra­aza­tricyclo­[16.4.0.0(7,12)]docosa­ne–(naphthalen-1-yl)methanol (1/2)

In the title co-crystal, C(20)H(40)N(4)·2C(11)H(10)O, the macrocycle is generated by a crystallographic inversion centre. The N atoms show a pyramidal coordination, and the cyclo­hexane ring that is fused to the 14-membered C(10)N(4) ring exists in a chair conformation, whereas the methyl substituen...

Descripción completa

Detalles Bibliográficos
Autores principales: Choi, Jong-Ha, Subhan, Md Abdus, Ryoo, Keon Sang, Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254450/
https://www.ncbi.nlm.nih.gov/pubmed/22259389
http://dx.doi.org/10.1107/S160053681105272X
Descripción
Sumario:In the title co-crystal, C(20)H(40)N(4)·2C(11)H(10)O, the macrocycle is generated by a crystallographic inversion centre. The N atoms show a pyramidal coordination, and the cyclo­hexane ring that is fused to the 14-membered C(10)N(4) ring exists in a chair conformation, whereas the methyl substituent occupies an axial site. The (naphthalen-1-yl)methanol mol­ecule forms an O—H⋯N hydrogen bond to a cyclam N atom. The mean-square-plane passing through the 14-membered ring is approximately coplanar with the naphthalene fused-ring [dihedral angle = 6.6 (1)°].

Ejemplares similares