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2-Chloro-N-{3-cyano-1-[2,6-dichloro-4-(trifluoro­meth­yl)phen­yl]-1H-pyrazol-5-yl}acetamide

The title compound, C(13)H(6)Cl(3)F(3)N(4)O, was synthesized by the reaction of 5-amino-1-[2,6-dichloro-4-(trifluoro­meth­yl)phen­yl]-1H-pyrazole-3-carbonitrile and 2-chloro­acetyl chloride. The five-membered pyrazole ring makes a dihedral angle of 71.5 (3)° with the benzene ring. The –CF(3) group i...

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Detalles Bibliográficos
Autores principales: Zhang, Jian-qiang, He, Qiu, Jiang, Qiang-hua, Mu, Hai-pin, Wan, Rong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254452/
https://www.ncbi.nlm.nih.gov/pubmed/22259391
http://dx.doi.org/10.1107/S1600536811052743
Descripción
Sumario:The title compound, C(13)H(6)Cl(3)F(3)N(4)O, was synthesized by the reaction of 5-amino-1-[2,6-dichloro-4-(trifluoro­meth­yl)phen­yl]-1H-pyrazole-3-carbonitrile and 2-chloro­acetyl chloride. The five-membered pyrazole ring makes a dihedral angle of 71.5 (3)° with the benzene ring. The –CF(3) group is disordered by rotation, and the F atoms are split over two sets of sites with occupancies of 0.59 (2) and 0.41 (2). The crystal structure features weak C—H⋯O and N—H⋯N inter­actions involving the carbonyl and cyano groups as acceptors.