N-[3-(4-Fluoro­benz­yl)-2,4-dioxo-1,3-diaza­spiro­[4.5]dec-8-yl]-2-methyl­benzene­sulfonamide

In the title compound, C(22)H(24)FN(3)O(4)S, the cyclo­hexane ring adopts a chair conformation and the five-membered ring is essentially planar, with a maximum deviation of 0.040 (2) Å. The dihedral angles between the five-membered ring and the tolyl and fluoro­benzene rings are 56.74 (12) and 89.88...

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Autores principales: Jeyaseelan, S., Vinduvahini, M., Madaiah, M., Bhattacharya, Suman, Revanasiddappa, H. D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254453/
https://www.ncbi.nlm.nih.gov/pubmed/22259392
http://dx.doi.org/10.1107/S160053681105269X
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author Jeyaseelan, S.
Vinduvahini, M.
Madaiah, M.
Bhattacharya, Suman
Revanasiddappa, H. D.
author_facet Jeyaseelan, S.
Vinduvahini, M.
Madaiah, M.
Bhattacharya, Suman
Revanasiddappa, H. D.
author_sort Jeyaseelan, S.
collection PubMed
description In the title compound, C(22)H(24)FN(3)O(4)S, the cyclo­hexane ring adopts a chair conformation and the five-membered ring is essentially planar, with a maximum deviation of 0.040 (2) Å. The dihedral angles between the five-membered ring and the tolyl and fluoro­benzene rings are 56.74 (12) and 89.88 (12)°, respectively. The two terminal benzene rings make a dihedral angle of 63.53 (12)°. The crystal structure displays inter­molecular C—H⋯O and N—H⋯O hydrogen bonds. An intra­molecular C—H⋯O hydrogen bond also occurs.
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spelling pubmed-32544532012-01-18 N-[3-(4-Fluoro­benz­yl)-2,4-dioxo-1,3-diaza­spiro­[4.5]dec-8-yl]-2-methyl­benzene­sulfonamide Jeyaseelan, S. Vinduvahini, M. Madaiah, M. Bhattacharya, Suman Revanasiddappa, H. D. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(22)H(24)FN(3)O(4)S, the cyclo­hexane ring adopts a chair conformation and the five-membered ring is essentially planar, with a maximum deviation of 0.040 (2) Å. The dihedral angles between the five-membered ring and the tolyl and fluoro­benzene rings are 56.74 (12) and 89.88 (12)°, respectively. The two terminal benzene rings make a dihedral angle of 63.53 (12)°. The crystal structure displays inter­molecular C—H⋯O and N—H⋯O hydrogen bonds. An intra­molecular C—H⋯O hydrogen bond also occurs. International Union of Crystallography 2011-12-14 /pmc/articles/PMC3254453/ /pubmed/22259392 http://dx.doi.org/10.1107/S160053681105269X Text en © Jeyaseelan et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Jeyaseelan, S.
Vinduvahini, M.
Madaiah, M.
Bhattacharya, Suman
Revanasiddappa, H. D.
N-[3-(4-Fluoro­benz­yl)-2,4-dioxo-1,3-diaza­spiro­[4.5]dec-8-yl]-2-methyl­benzene­sulfonamide
title N-[3-(4-Fluoro­benz­yl)-2,4-dioxo-1,3-diaza­spiro­[4.5]dec-8-yl]-2-methyl­benzene­sulfonamide
title_full N-[3-(4-Fluoro­benz­yl)-2,4-dioxo-1,3-diaza­spiro­[4.5]dec-8-yl]-2-methyl­benzene­sulfonamide
title_fullStr N-[3-(4-Fluoro­benz­yl)-2,4-dioxo-1,3-diaza­spiro­[4.5]dec-8-yl]-2-methyl­benzene­sulfonamide
title_full_unstemmed N-[3-(4-Fluoro­benz­yl)-2,4-dioxo-1,3-diaza­spiro­[4.5]dec-8-yl]-2-methyl­benzene­sulfonamide
title_short N-[3-(4-Fluoro­benz­yl)-2,4-dioxo-1,3-diaza­spiro­[4.5]dec-8-yl]-2-methyl­benzene­sulfonamide
title_sort n-[3-(4-fluoro­benz­yl)-2,4-dioxo-1,3-diaza­spiro­[4.5]dec-8-yl]-2-methyl­benzene­sulfonamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254453/
https://www.ncbi.nlm.nih.gov/pubmed/22259392
http://dx.doi.org/10.1107/S160053681105269X
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