20,23,26,29,32,35,38,41-Octa­oxa-5,9,13-triaza­penta­cyclo­[15.14.10.1(3,30).1(7,11).1(15,19)]tetra­tetra­conta-1,3(42),7,9,11(44),15(43),16,18,30-nona­ene-6,12-dione acetone mono­solvate

In the crystal structure of the title compound, C(33)H(39)N(3)O(10)·C(3)H(6)O, the acetone mol­ecule is encapsulated into the cavity of the cryptand and fixed by two N—H⋯O and one C—H⋯O hydrogen bond. C—H⋯O and C—H⋯N inter­actions link neighbouring cryptands. The dihedral angles between the pyridine...

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Detalles Bibliográficos
Autores principales: Pan, Shaowu, Yang, Dengke, Yang, Yu, Jiang, Lasheng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254454/
https://www.ncbi.nlm.nih.gov/pubmed/22259393
http://dx.doi.org/10.1107/S1600536811051877
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author Pan, Shaowu
Yang, Dengke
Yang, Yu
Jiang, Lasheng
author_facet Pan, Shaowu
Yang, Dengke
Yang, Yu
Jiang, Lasheng
author_sort Pan, Shaowu
collection PubMed
description In the crystal structure of the title compound, C(33)H(39)N(3)O(10)·C(3)H(6)O, the acetone mol­ecule is encapsulated into the cavity of the cryptand and fixed by two N—H⋯O and one C—H⋯O hydrogen bond. C—H⋯O and C—H⋯N inter­actions link neighbouring cryptands. The dihedral angles between the pyridine ring and the benzene rings are 86.47 (17) and 85.53 (13)°.
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spelling pubmed-32544542012-01-18 20,23,26,29,32,35,38,41-Octa­oxa-5,9,13-triaza­penta­cyclo­[15.14.10.1(3,30).1(7,11).1(15,19)]tetra­tetra­conta-1,3(42),7,9,11(44),15(43),16,18,30-nona­ene-6,12-dione acetone mono­solvate Pan, Shaowu Yang, Dengke Yang, Yu Jiang, Lasheng Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, C(33)H(39)N(3)O(10)·C(3)H(6)O, the acetone mol­ecule is encapsulated into the cavity of the cryptand and fixed by two N—H⋯O and one C—H⋯O hydrogen bond. C—H⋯O and C—H⋯N inter­actions link neighbouring cryptands. The dihedral angles between the pyridine ring and the benzene rings are 86.47 (17) and 85.53 (13)°. International Union of Crystallography 2011-12-14 /pmc/articles/PMC3254454/ /pubmed/22259393 http://dx.doi.org/10.1107/S1600536811051877 Text en © Pan et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Pan, Shaowu
Yang, Dengke
Yang, Yu
Jiang, Lasheng
20,23,26,29,32,35,38,41-Octa­oxa-5,9,13-triaza­penta­cyclo­[15.14.10.1(3,30).1(7,11).1(15,19)]tetra­tetra­conta-1,3(42),7,9,11(44),15(43),16,18,30-nona­ene-6,12-dione acetone mono­solvate
title 20,23,26,29,32,35,38,41-Octa­oxa-5,9,13-triaza­penta­cyclo­[15.14.10.1(3,30).1(7,11).1(15,19)]tetra­tetra­conta-1,3(42),7,9,11(44),15(43),16,18,30-nona­ene-6,12-dione acetone mono­solvate
title_full 20,23,26,29,32,35,38,41-Octa­oxa-5,9,13-triaza­penta­cyclo­[15.14.10.1(3,30).1(7,11).1(15,19)]tetra­tetra­conta-1,3(42),7,9,11(44),15(43),16,18,30-nona­ene-6,12-dione acetone mono­solvate
title_fullStr 20,23,26,29,32,35,38,41-Octa­oxa-5,9,13-triaza­penta­cyclo­[15.14.10.1(3,30).1(7,11).1(15,19)]tetra­tetra­conta-1,3(42),7,9,11(44),15(43),16,18,30-nona­ene-6,12-dione acetone mono­solvate
title_full_unstemmed 20,23,26,29,32,35,38,41-Octa­oxa-5,9,13-triaza­penta­cyclo­[15.14.10.1(3,30).1(7,11).1(15,19)]tetra­tetra­conta-1,3(42),7,9,11(44),15(43),16,18,30-nona­ene-6,12-dione acetone mono­solvate
title_short 20,23,26,29,32,35,38,41-Octa­oxa-5,9,13-triaza­penta­cyclo­[15.14.10.1(3,30).1(7,11).1(15,19)]tetra­tetra­conta-1,3(42),7,9,11(44),15(43),16,18,30-nona­ene-6,12-dione acetone mono­solvate
title_sort 20,23,26,29,32,35,38,41-octa­oxa-5,9,13-triaza­penta­cyclo­[15.14.10.1(3,30).1(7,11).1(15,19)]tetra­tetra­conta-1,3(42),7,9,11(44),15(43),16,18,30-nona­ene-6,12-dione acetone mono­solvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254454/
https://www.ncbi.nlm.nih.gov/pubmed/22259393
http://dx.doi.org/10.1107/S1600536811051877
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AT yangdengke 2023262932353841octaoxa5913triazapentacyclo1514101330171111519tetratetraconta13427911441543161830nonaene612dioneacetonemonosolvate
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