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2-Amino-5-chloro­pyrimidin-1-ium hydrogen maleate

In the title salt, C(4)H(5)ClN(3) (+)·C(4)H(3)O(4) (−), the 2-amino-5-chloro­pyrimidinium cation is protonated at one of its pyrimidine N atoms. In the roughly planar (r.m.s. deviation = 0.026 Å) hydrogen malate anion, an intra­molecular O—H⋯O hydrogen bond generates an S(7) ring. In the crystal, th...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Hemamalini, Madhukar, Rajakannan, Venkatachalam
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254455/
https://www.ncbi.nlm.nih.gov/pubmed/22259394
http://dx.doi.org/10.1107/S1600536811051646
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author Fun, Hoong-Kun
Hemamalini, Madhukar
Rajakannan, Venkatachalam
author_facet Fun, Hoong-Kun
Hemamalini, Madhukar
Rajakannan, Venkatachalam
author_sort Fun, Hoong-Kun
collection PubMed
description In the title salt, C(4)H(5)ClN(3) (+)·C(4)H(3)O(4) (−), the 2-amino-5-chloro­pyrimidinium cation is protonated at one of its pyrimidine N atoms. In the roughly planar (r.m.s. deviation = 0.026 Å) hydrogen malate anion, an intra­molecular O—H⋯O hydrogen bond generates an S(7) ring. In the crystal, the protonated N atom and the 2-amino group of the cation are hydrogen bonded to the carboxyl­ate O atoms of the anion via a pair of N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. The ion pairs are connected via further N—H⋯O hydrogen bonds and a short C—H⋯O inter­action, forming layers lying parallel to the bc plane.
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spelling pubmed-32544552012-01-18 2-Amino-5-chloro­pyrimidin-1-ium hydrogen maleate Fun, Hoong-Kun Hemamalini, Madhukar Rajakannan, Venkatachalam Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title salt, C(4)H(5)ClN(3) (+)·C(4)H(3)O(4) (−), the 2-amino-5-chloro­pyrimidinium cation is protonated at one of its pyrimidine N atoms. In the roughly planar (r.m.s. deviation = 0.026 Å) hydrogen malate anion, an intra­molecular O—H⋯O hydrogen bond generates an S(7) ring. In the crystal, the protonated N atom and the 2-amino group of the cation are hydrogen bonded to the carboxyl­ate O atoms of the anion via a pair of N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. The ion pairs are connected via further N—H⋯O hydrogen bonds and a short C—H⋯O inter­action, forming layers lying parallel to the bc plane. International Union of Crystallography 2011-12-14 /pmc/articles/PMC3254455/ /pubmed/22259394 http://dx.doi.org/10.1107/S1600536811051646 Text en © Fun et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Hemamalini, Madhukar
Rajakannan, Venkatachalam
2-Amino-5-chloro­pyrimidin-1-ium hydrogen maleate
title 2-Amino-5-chloro­pyrimidin-1-ium hydrogen maleate
title_full 2-Amino-5-chloro­pyrimidin-1-ium hydrogen maleate
title_fullStr 2-Amino-5-chloro­pyrimidin-1-ium hydrogen maleate
title_full_unstemmed 2-Amino-5-chloro­pyrimidin-1-ium hydrogen maleate
title_short 2-Amino-5-chloro­pyrimidin-1-ium hydrogen maleate
title_sort 2-amino-5-chloro­pyrimidin-1-ium hydrogen maleate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254455/
https://www.ncbi.nlm.nih.gov/pubmed/22259394
http://dx.doi.org/10.1107/S1600536811051646
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