1-Benzoyl-3-(2,4,5-trichloro­phen­yl)thio­urea

The benzene and phenyl rings in the title compound, C(14)H(9)Cl(3)N(2)OS, form a dihedral angle of 40.98 (6)°. The mol­ecule exists in the thione form with typical thio­urea C—S [1.666 (2) Å] and C—O [1.227 (3) Å] bond lengths as well as shortened C—N bonds [1.345 (3) and 1.386 (2) Å]. An intra­mole...

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Autores principales: Rauf, M. Khawar, Ebihara, Masahiro, Badshah, Amin, Imtiaz-ud-Din
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254466/
https://www.ncbi.nlm.nih.gov/pubmed/22259406
http://dx.doi.org/10.1107/S1600536811052780
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author Rauf, M. Khawar
Ebihara, Masahiro
Badshah, Amin
Imtiaz-ud-Din,
author_facet Rauf, M. Khawar
Ebihara, Masahiro
Badshah, Amin
Imtiaz-ud-Din,
author_sort Rauf, M. Khawar
collection PubMed
description The benzene and phenyl rings in the title compound, C(14)H(9)Cl(3)N(2)OS, form a dihedral angle of 40.98 (6)°. The mol­ecule exists in the thione form with typical thio­urea C—S [1.666 (2) Å] and C—O [1.227 (3) Å] bond lengths as well as shortened C—N bonds [1.345 (3) and 1.386 (2) Å]. An intra­molecular N—H⋯O hydrogen bond stabilizes the mol­ecular conformation. In the crystal, pairs of N—H⋯S hydrogen bonds link the mol­ecules into centrosymmetric dimers.
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spelling pubmed-32544662012-01-18 1-Benzoyl-3-(2,4,5-trichloro­phen­yl)thio­urea Rauf, M. Khawar Ebihara, Masahiro Badshah, Amin Imtiaz-ud-Din, Acta Crystallogr Sect E Struct Rep Online Organic Papers The benzene and phenyl rings in the title compound, C(14)H(9)Cl(3)N(2)OS, form a dihedral angle of 40.98 (6)°. The mol­ecule exists in the thione form with typical thio­urea C—S [1.666 (2) Å] and C—O [1.227 (3) Å] bond lengths as well as shortened C—N bonds [1.345 (3) and 1.386 (2) Å]. An intra­molecular N—H⋯O hydrogen bond stabilizes the mol­ecular conformation. In the crystal, pairs of N—H⋯S hydrogen bonds link the mol­ecules into centrosymmetric dimers. International Union of Crystallography 2011-12-14 /pmc/articles/PMC3254466/ /pubmed/22259406 http://dx.doi.org/10.1107/S1600536811052780 Text en © Rauf et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Rauf, M. Khawar
Ebihara, Masahiro
Badshah, Amin
Imtiaz-ud-Din,
1-Benzoyl-3-(2,4,5-trichloro­phen­yl)thio­urea
title 1-Benzoyl-3-(2,4,5-trichloro­phen­yl)thio­urea
title_full 1-Benzoyl-3-(2,4,5-trichloro­phen­yl)thio­urea
title_fullStr 1-Benzoyl-3-(2,4,5-trichloro­phen­yl)thio­urea
title_full_unstemmed 1-Benzoyl-3-(2,4,5-trichloro­phen­yl)thio­urea
title_short 1-Benzoyl-3-(2,4,5-trichloro­phen­yl)thio­urea
title_sort 1-benzoyl-3-(2,4,5-trichloro­phen­yl)thio­urea
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254466/
https://www.ncbi.nlm.nih.gov/pubmed/22259406
http://dx.doi.org/10.1107/S1600536811052780
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AT imtiazuddin 1benzoyl3245trichlorophenylthiourea

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