4,6-Dichloro-2-{[(E)-(3-{[(E)-3,5-dichloro-2-hy­droxy­benzyl­idene]amino}-2,2-dimethyl­prop­yl)imino]­meth­yl}phenol

In the title compound, C(19)H(18)Cl(4)N(2)O(2), a potential tetra­dentate Schiff base ligand, the dihedral angle between the two benzene rings is 48.01 (10)°. The configuration about the two C=N bonds is E and two intra­molecular O—H⋯N hydrogen bonds make S(6) ring motifs. In the crystal, mol­ecules...

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Detalles Bibliográficos
Autores principales: Kargar, Hadi, Kia, Reza, Abbasian, Saeideh, Tahir, Muhammad Nawaz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254485/
https://www.ncbi.nlm.nih.gov/pubmed/22259428
http://dx.doi.org/10.1107/S1600536811053438
Descripción
Sumario:In the title compound, C(19)H(18)Cl(4)N(2)O(2), a potential tetra­dentate Schiff base ligand, the dihedral angle between the two benzene rings is 48.01 (10)°. The configuration about the two C=N bonds is E and two intra­molecular O—H⋯N hydrogen bonds make S(6) ring motifs. In the crystal, mol­ecules are linked along the b axis via inter­molecular C—H⋯Cl inter­actions. The crystal structure is further stabilized by an inter­molecular π–π inter­action [centroid–centroid distance = 3.5744 (12) Å].

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