4,6-Dichloro-2-{[(E)-(3-{[(E)-3,5-dichloro-2-hy­droxy­benzyl­idene]amino}-2,2-dimethyl­prop­yl)imino]­meth­yl}phenol

In the title compound, C(19)H(18)Cl(4)N(2)O(2), a potential tetra­dentate Schiff base ligand, the dihedral angle between the two benzene rings is 48.01 (10)°. The configuration about the two C=N bonds is E and two intra­molecular O—H⋯N hydrogen bonds make S(6) ring motifs. In the crystal, mol­ecules...

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Detalles Bibliográficos
Autores principales: Kargar, Hadi, Kia, Reza, Abbasian, Saeideh, Tahir, Muhammad Nawaz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254485/
https://www.ncbi.nlm.nih.gov/pubmed/22259428
http://dx.doi.org/10.1107/S1600536811053438
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author Kargar, Hadi
Kia, Reza
Abbasian, Saeideh
Tahir, Muhammad Nawaz
author_facet Kargar, Hadi
Kia, Reza
Abbasian, Saeideh
Tahir, Muhammad Nawaz
author_sort Kargar, Hadi
collection PubMed
description In the title compound, C(19)H(18)Cl(4)N(2)O(2), a potential tetra­dentate Schiff base ligand, the dihedral angle between the two benzene rings is 48.01 (10)°. The configuration about the two C=N bonds is E and two intra­molecular O—H⋯N hydrogen bonds make S(6) ring motifs. In the crystal, mol­ecules are linked along the b axis via inter­molecular C—H⋯Cl inter­actions. The crystal structure is further stabilized by an inter­molecular π–π inter­action [centroid–centroid distance = 3.5744 (12) Å].
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spelling pubmed-32544852012-01-18 4,6-Dichloro-2-{[(E)-(3-{[(E)-3,5-dichloro-2-hy­droxy­benzyl­idene]amino}-2,2-dimethyl­prop­yl)imino]­meth­yl}phenol Kargar, Hadi Kia, Reza Abbasian, Saeideh Tahir, Muhammad Nawaz Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(19)H(18)Cl(4)N(2)O(2), a potential tetra­dentate Schiff base ligand, the dihedral angle between the two benzene rings is 48.01 (10)°. The configuration about the two C=N bonds is E and two intra­molecular O—H⋯N hydrogen bonds make S(6) ring motifs. In the crystal, mol­ecules are linked along the b axis via inter­molecular C—H⋯Cl inter­actions. The crystal structure is further stabilized by an inter­molecular π–π inter­action [centroid–centroid distance = 3.5744 (12) Å]. International Union of Crystallography 2011-12-17 /pmc/articles/PMC3254485/ /pubmed/22259428 http://dx.doi.org/10.1107/S1600536811053438 Text en © Kargar et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kargar, Hadi
Kia, Reza
Abbasian, Saeideh
Tahir, Muhammad Nawaz
4,6-Dichloro-2-{[(E)-(3-{[(E)-3,5-dichloro-2-hy­droxy­benzyl­idene]amino}-2,2-dimethyl­prop­yl)imino]­meth­yl}phenol
title 4,6-Dichloro-2-{[(E)-(3-{[(E)-3,5-dichloro-2-hy­droxy­benzyl­idene]amino}-2,2-dimethyl­prop­yl)imino]­meth­yl}phenol
title_full 4,6-Dichloro-2-{[(E)-(3-{[(E)-3,5-dichloro-2-hy­droxy­benzyl­idene]amino}-2,2-dimethyl­prop­yl)imino]­meth­yl}phenol
title_fullStr 4,6-Dichloro-2-{[(E)-(3-{[(E)-3,5-dichloro-2-hy­droxy­benzyl­idene]amino}-2,2-dimethyl­prop­yl)imino]­meth­yl}phenol
title_full_unstemmed 4,6-Dichloro-2-{[(E)-(3-{[(E)-3,5-dichloro-2-hy­droxy­benzyl­idene]amino}-2,2-dimethyl­prop­yl)imino]­meth­yl}phenol
title_short 4,6-Dichloro-2-{[(E)-(3-{[(E)-3,5-dichloro-2-hy­droxy­benzyl­idene]amino}-2,2-dimethyl­prop­yl)imino]­meth­yl}phenol
title_sort 4,6-dichloro-2-{[(e)-(3-{[(e)-3,5-dichloro-2-hy­droxy­benzyl­idene]amino}-2,2-dimethyl­prop­yl)imino]­meth­yl}phenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254485/
https://www.ncbi.nlm.nih.gov/pubmed/22259428
http://dx.doi.org/10.1107/S1600536811053438
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AT abbasiansaeideh 46dichloro2e3e35dichloro2hydroxybenzylideneamino22dimethylpropyliminomethylphenol
AT tahirmuhammadnawaz 46dichloro2e3e35dichloro2hydroxybenzylideneamino22dimethylpropyliminomethylphenol

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