2-(6-Chloro-1H-indol-3-yl)acetonitrile

In the title compound, C(10)H(7)ClN(2), the carbonitrile group is twisted away from the plane of the indole ring system [C(cy)—C(me)—C(ar)—C(ar) = −44.7 (8)°; cy = cyanide, me = methyl­ene and ar = aromatic]. In the crystal, N—H⋯N hydrogen bonds link the mol­ecules into C(7) chains propagating in [0...

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Detalles Bibliográficos
Autores principales: Li, Jin-Feng, Luo, Yang-Hui
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254487/
https://www.ncbi.nlm.nih.gov/pubmed/22259430
http://dx.doi.org/10.1107/S1600536811053372
Descripción
Sumario:In the title compound, C(10)H(7)ClN(2), the carbonitrile group is twisted away from the plane of the indole ring system [C(cy)—C(me)—C(ar)—C(ar) = −44.7 (8)°; cy = cyanide, me = methyl­ene and ar = aromatic]. In the crystal, N—H⋯N hydrogen bonds link the mol­ecules into C(7) chains propagating in [010]. Aromatic π–π stacking inter­actions [minimum centroid–centroid separation = 3.663 (3) Å] are also observed.

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