2-(6-Chloro-1H-indol-3-yl)acetonitrile

In the title compound, C(10)H(7)ClN(2), the carbonitrile group is twisted away from the plane of the indole ring system [C(cy)—C(me)—C(ar)—C(ar) = −44.7 (8)°; cy = cyanide, me = methyl­ene and ar = aromatic]. In the crystal, N—H⋯N hydrogen bonds link the mol­ecules into C(7) chains propagating in [0...

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Detalles Bibliográficos
Autores principales: Li, Jin-Feng, Luo, Yang-Hui
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254487/
https://www.ncbi.nlm.nih.gov/pubmed/22259430
http://dx.doi.org/10.1107/S1600536811053372
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author Li, Jin-Feng
Luo, Yang-Hui
author_facet Li, Jin-Feng
Luo, Yang-Hui
author_sort Li, Jin-Feng
collection PubMed
description In the title compound, C(10)H(7)ClN(2), the carbonitrile group is twisted away from the plane of the indole ring system [C(cy)—C(me)—C(ar)—C(ar) = −44.7 (8)°; cy = cyanide, me = methyl­ene and ar = aromatic]. In the crystal, N—H⋯N hydrogen bonds link the mol­ecules into C(7) chains propagating in [010]. Aromatic π–π stacking inter­actions [minimum centroid–centroid separation = 3.663 (3) Å] are also observed.
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spelling pubmed-32544872012-01-18 2-(6-Chloro-1H-indol-3-yl)acetonitrile Li, Jin-Feng Luo, Yang-Hui Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(10)H(7)ClN(2), the carbonitrile group is twisted away from the plane of the indole ring system [C(cy)—C(me)—C(ar)—C(ar) = −44.7 (8)°; cy = cyanide, me = methyl­ene and ar = aromatic]. In the crystal, N—H⋯N hydrogen bonds link the mol­ecules into C(7) chains propagating in [010]. Aromatic π–π stacking inter­actions [minimum centroid–centroid separation = 3.663 (3) Å] are also observed. International Union of Crystallography 2011-12-17 /pmc/articles/PMC3254487/ /pubmed/22259430 http://dx.doi.org/10.1107/S1600536811053372 Text en © Li and Luo 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Jin-Feng
Luo, Yang-Hui
2-(6-Chloro-1H-indol-3-yl)acetonitrile
title 2-(6-Chloro-1H-indol-3-yl)acetonitrile
title_full 2-(6-Chloro-1H-indol-3-yl)acetonitrile
title_fullStr 2-(6-Chloro-1H-indol-3-yl)acetonitrile
title_full_unstemmed 2-(6-Chloro-1H-indol-3-yl)acetonitrile
title_short 2-(6-Chloro-1H-indol-3-yl)acetonitrile
title_sort 2-(6-chloro-1h-indol-3-yl)acetonitrile
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254487/
https://www.ncbi.nlm.nih.gov/pubmed/22259430
http://dx.doi.org/10.1107/S1600536811053372
work_keys_str_mv AT lijinfeng 26chloro1hindol3ylacetonitrile
AT luoyanghui 26chloro1hindol3ylacetonitrile

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