1-[(6-Chloro­pyridin-3-yl)meth­yl]imidazolidin-2-iminium chloride

The title compound, C(9)H(12)ClN(4) (+)·Cl(−), is a natural metabolic product of imidacloprid [systematic name: (E)-1-(6-chloro-3-pyridyl­meth­yl)-N-nitro­imidazolidin-2-yl­idene­amine] and was obtained by the reduction of the latter using Fe in HCl. The dihedral angle between the pyridine and imida...

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Autores principales: Kant, Rajni, Gupta, Vivek K., Kapoor, Kamini, Deshmukh, Madhukar B., Shripanavar, Chetan S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254490/
https://www.ncbi.nlm.nih.gov/pubmed/22259433
http://dx.doi.org/10.1107/S1600536811053487
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author Kant, Rajni
Gupta, Vivek K.
Kapoor, Kamini
Deshmukh, Madhukar B.
Shripanavar, Chetan S.
author_facet Kant, Rajni
Gupta, Vivek K.
Kapoor, Kamini
Deshmukh, Madhukar B.
Shripanavar, Chetan S.
author_sort Kant, Rajni
collection PubMed
description The title compound, C(9)H(12)ClN(4) (+)·Cl(−), is a natural metabolic product of imidacloprid [systematic name: (E)-1-(6-chloro-3-pyridyl­meth­yl)-N-nitro­imidazolidin-2-yl­idene­amine] and was obtained by the reduction of the latter using Fe in HCl. The dihedral angle between the pyridine and imidazole rings is 62.09 (12)°. The crystal structure is stabilized by N—H⋯Cl and C—H⋯Cl inter­actions involving the chloride anion. The pyridine N and the chloride atoms are not involved in inter­molecular inter­actions.
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spelling pubmed-32544902012-01-18 1-[(6-Chloro­pyridin-3-yl)meth­yl]imidazolidin-2-iminium chloride Kant, Rajni Gupta, Vivek K. Kapoor, Kamini Deshmukh, Madhukar B. Shripanavar, Chetan S. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(9)H(12)ClN(4) (+)·Cl(−), is a natural metabolic product of imidacloprid [systematic name: (E)-1-(6-chloro-3-pyridyl­meth­yl)-N-nitro­imidazolidin-2-yl­idene­amine] and was obtained by the reduction of the latter using Fe in HCl. The dihedral angle between the pyridine and imidazole rings is 62.09 (12)°. The crystal structure is stabilized by N—H⋯Cl and C—H⋯Cl inter­actions involving the chloride anion. The pyridine N and the chloride atoms are not involved in inter­molecular inter­actions. International Union of Crystallography 2011-12-17 /pmc/articles/PMC3254490/ /pubmed/22259433 http://dx.doi.org/10.1107/S1600536811053487 Text en © Kant et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kant, Rajni
Gupta, Vivek K.
Kapoor, Kamini
Deshmukh, Madhukar B.
Shripanavar, Chetan S.
1-[(6-Chloro­pyridin-3-yl)meth­yl]imidazolidin-2-iminium chloride
title 1-[(6-Chloro­pyridin-3-yl)meth­yl]imidazolidin-2-iminium chloride
title_full 1-[(6-Chloro­pyridin-3-yl)meth­yl]imidazolidin-2-iminium chloride
title_fullStr 1-[(6-Chloro­pyridin-3-yl)meth­yl]imidazolidin-2-iminium chloride
title_full_unstemmed 1-[(6-Chloro­pyridin-3-yl)meth­yl]imidazolidin-2-iminium chloride
title_short 1-[(6-Chloro­pyridin-3-yl)meth­yl]imidazolidin-2-iminium chloride
title_sort 1-[(6-chloro­pyridin-3-yl)meth­yl]imidazolidin-2-iminium chloride
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254490/
https://www.ncbi.nlm.nih.gov/pubmed/22259433
http://dx.doi.org/10.1107/S1600536811053487
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