(E)-3,3′-(Diazene-1,2-di­yl)bis­(1-methyl-1,4,5,6-tetra­hydro­pyrrolo­[3,4-c]pyrazol-5-ium) dinitrate dihydrate

The title compound, C(12)H(18)N(8) (2+)·2NO(3) (−)·2H(2)O, was synthesized unexpectedly from 3-amino-1-methyl-1,4,5,6-tetra­hydro­pyrrolo­[3,4-c]pyrazol-5-ium chloride and cerium(IV) ammonium nitrate. The cation has a crystallographically imposed centre of symmetry. In the crystal, the ions and wate...

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Detalles Bibliográficos
Autores principales: Chen, Jin-Mei, Zhao, Hong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254494/
https://www.ncbi.nlm.nih.gov/pubmed/22259437
http://dx.doi.org/10.1107/S1600536811053347
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author Chen, Jin-Mei
Zhao, Hong
author_facet Chen, Jin-Mei
Zhao, Hong
author_sort Chen, Jin-Mei
collection PubMed
description The title compound, C(12)H(18)N(8) (2+)·2NO(3) (−)·2H(2)O, was synthesized unexpectedly from 3-amino-1-methyl-1,4,5,6-tetra­hydro­pyrrolo­[3,4-c]pyrazol-5-ium chloride and cerium(IV) ammonium nitrate. The cation has a crystallographically imposed centre of symmetry. In the crystal, the ions and water mol­ecules are linked via O—H⋯N, N—H⋯O and O—H⋯O hydrogen bonds into a three-dimensional network.
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spelling pubmed-32544942012-01-18 (E)-3,3′-(Diazene-1,2-di­yl)bis­(1-methyl-1,4,5,6-tetra­hydro­pyrrolo­[3,4-c]pyrazol-5-ium) dinitrate dihydrate Chen, Jin-Mei Zhao, Hong Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(12)H(18)N(8) (2+)·2NO(3) (−)·2H(2)O, was synthesized unexpectedly from 3-amino-1-methyl-1,4,5,6-tetra­hydro­pyrrolo­[3,4-c]pyrazol-5-ium chloride and cerium(IV) ammonium nitrate. The cation has a crystallographically imposed centre of symmetry. In the crystal, the ions and water mol­ecules are linked via O—H⋯N, N—H⋯O and O—H⋯O hydrogen bonds into a three-dimensional network. International Union of Crystallography 2011-12-17 /pmc/articles/PMC3254494/ /pubmed/22259437 http://dx.doi.org/10.1107/S1600536811053347 Text en © Chen and Zhao 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Chen, Jin-Mei
Zhao, Hong
(E)-3,3′-(Diazene-1,2-di­yl)bis­(1-methyl-1,4,5,6-tetra­hydro­pyrrolo­[3,4-c]pyrazol-5-ium) dinitrate dihydrate
title (E)-3,3′-(Diazene-1,2-di­yl)bis­(1-methyl-1,4,5,6-tetra­hydro­pyrrolo­[3,4-c]pyrazol-5-ium) dinitrate dihydrate
title_full (E)-3,3′-(Diazene-1,2-di­yl)bis­(1-methyl-1,4,5,6-tetra­hydro­pyrrolo­[3,4-c]pyrazol-5-ium) dinitrate dihydrate
title_fullStr (E)-3,3′-(Diazene-1,2-di­yl)bis­(1-methyl-1,4,5,6-tetra­hydro­pyrrolo­[3,4-c]pyrazol-5-ium) dinitrate dihydrate
title_full_unstemmed (E)-3,3′-(Diazene-1,2-di­yl)bis­(1-methyl-1,4,5,6-tetra­hydro­pyrrolo­[3,4-c]pyrazol-5-ium) dinitrate dihydrate
title_short (E)-3,3′-(Diazene-1,2-di­yl)bis­(1-methyl-1,4,5,6-tetra­hydro­pyrrolo­[3,4-c]pyrazol-5-ium) dinitrate dihydrate
title_sort (e)-3,3′-(diazene-1,2-di­yl)bis­(1-methyl-1,4,5,6-tetra­hydro­pyrrolo­[3,4-c]pyrazol-5-ium) dinitrate dihydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254494/
https://www.ncbi.nlm.nih.gov/pubmed/22259437
http://dx.doi.org/10.1107/S1600536811053347
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AT zhaohong e33diazene12diylbis1methyl1456tetrahydropyrrolo34cpyrazol5iumdinitratedihydrate

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