Methyl (Z)-2-[(2,4-dioxothia­zolidin-3-yl)meth­yl]-3-(2-methyl­phen­yl)prop-2-enoate

The C=C bond in the title compound, C(15)H(15)NO(4)S, has a Z configuration. The thia­zolidine ring is essentially planar [maximum deviation = 0.008 (1) Å for the N atom] and is oriented at a dihedral angle of 59.1 (1)° with respect to the benzene ring. In the crystal, pairs of C—H⋯O hydrogen bonds...

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Autores principales: Vijayakumar, S., Murugavel, S., Kannan, D., Bakthadoss, M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254499/
https://www.ncbi.nlm.nih.gov/pubmed/22259442
http://dx.doi.org/10.1107/S1600536811053682
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author Vijayakumar, S.
Murugavel, S.
Kannan, D.
Bakthadoss, M.
author_facet Vijayakumar, S.
Murugavel, S.
Kannan, D.
Bakthadoss, M.
author_sort Vijayakumar, S.
collection PubMed
description The C=C bond in the title compound, C(15)H(15)NO(4)S, has a Z configuration. The thia­zolidine ring is essentially planar [maximum deviation = 0.008 (1) Å for the N atom] and is oriented at a dihedral angle of 59.1 (1)° with respect to the benzene ring. In the crystal, pairs of C—H⋯O hydrogen bonds link centrosymmetrically related mol­ecules into dimers, generating R (2) (2)(18) ring motifs. The crystal packing is further stabilized by C—H⋯π and C—O⋯π [O⋯centroid = 3.412 (2) Å and C—O⋯centroid = 115.0 (1)°] inter­actions.
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spelling pubmed-32544992012-01-18 Methyl (Z)-2-[(2,4-dioxothia­zolidin-3-yl)meth­yl]-3-(2-methyl­phen­yl)prop-2-enoate Vijayakumar, S. Murugavel, S. Kannan, D. Bakthadoss, M. Acta Crystallogr Sect E Struct Rep Online Organic Papers The C=C bond in the title compound, C(15)H(15)NO(4)S, has a Z configuration. The thia­zolidine ring is essentially planar [maximum deviation = 0.008 (1) Å for the N atom] and is oriented at a dihedral angle of 59.1 (1)° with respect to the benzene ring. In the crystal, pairs of C—H⋯O hydrogen bonds link centrosymmetrically related mol­ecules into dimers, generating R (2) (2)(18) ring motifs. The crystal packing is further stabilized by C—H⋯π and C—O⋯π [O⋯centroid = 3.412 (2) Å and C—O⋯centroid = 115.0 (1)°] inter­actions. International Union of Crystallography 2011-12-17 /pmc/articles/PMC3254499/ /pubmed/22259442 http://dx.doi.org/10.1107/S1600536811053682 Text en © Vijayakumar et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Vijayakumar, S.
Murugavel, S.
Kannan, D.
Bakthadoss, M.
Methyl (Z)-2-[(2,4-dioxothia­zolidin-3-yl)meth­yl]-3-(2-methyl­phen­yl)prop-2-enoate
title Methyl (Z)-2-[(2,4-dioxothia­zolidin-3-yl)meth­yl]-3-(2-methyl­phen­yl)prop-2-enoate
title_full Methyl (Z)-2-[(2,4-dioxothia­zolidin-3-yl)meth­yl]-3-(2-methyl­phen­yl)prop-2-enoate
title_fullStr Methyl (Z)-2-[(2,4-dioxothia­zolidin-3-yl)meth­yl]-3-(2-methyl­phen­yl)prop-2-enoate
title_full_unstemmed Methyl (Z)-2-[(2,4-dioxothia­zolidin-3-yl)meth­yl]-3-(2-methyl­phen­yl)prop-2-enoate
title_short Methyl (Z)-2-[(2,4-dioxothia­zolidin-3-yl)meth­yl]-3-(2-methyl­phen­yl)prop-2-enoate
title_sort methyl (z)-2-[(2,4-dioxothia­zolidin-3-yl)meth­yl]-3-(2-methyl­phen­yl)prop-2-enoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254499/
https://www.ncbi.nlm.nih.gov/pubmed/22259442
http://dx.doi.org/10.1107/S1600536811053682
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AT kannand methylz224dioxothiazolidin3ylmethyl32methylphenylprop2enoate
AT bakthadossm methylz224dioxothiazolidin3ylmethyl32methylphenylprop2enoate

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