Cargando…
Methyl (Z)-2-[(2,4-dioxothiazolidin-3-yl)methyl]-3-(2-methylphenyl)prop-2-enoate
The C=C bond in the title compound, C(15)H(15)NO(4)S, has a Z configuration. The thiazolidine ring is essentially planar [maximum deviation = 0.008 (1) Å for the N atom] and is oriented at a dihedral angle of 59.1 (1)° with respect to the benzene ring. In the crystal, pairs of C—H⋯O hydrogen bonds...
Autores principales: | , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254499/ https://www.ncbi.nlm.nih.gov/pubmed/22259442 http://dx.doi.org/10.1107/S1600536811053682 |
_version_ | 1782220867791486976 |
---|---|
author | Vijayakumar, S. Murugavel, S. Kannan, D. Bakthadoss, M. |
author_facet | Vijayakumar, S. Murugavel, S. Kannan, D. Bakthadoss, M. |
author_sort | Vijayakumar, S. |
collection | PubMed |
description | The C=C bond in the title compound, C(15)H(15)NO(4)S, has a Z configuration. The thiazolidine ring is essentially planar [maximum deviation = 0.008 (1) Å for the N atom] and is oriented at a dihedral angle of 59.1 (1)° with respect to the benzene ring. In the crystal, pairs of C—H⋯O hydrogen bonds link centrosymmetrically related molecules into dimers, generating R (2) (2)(18) ring motifs. The crystal packing is further stabilized by C—H⋯π and C—O⋯π [O⋯centroid = 3.412 (2) Å and C—O⋯centroid = 115.0 (1)°] interactions. |
format | Online Article Text |
id | pubmed-3254499 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32544992012-01-18 Methyl (Z)-2-[(2,4-dioxothiazolidin-3-yl)methyl]-3-(2-methylphenyl)prop-2-enoate Vijayakumar, S. Murugavel, S. Kannan, D. Bakthadoss, M. Acta Crystallogr Sect E Struct Rep Online Organic Papers The C=C bond in the title compound, C(15)H(15)NO(4)S, has a Z configuration. The thiazolidine ring is essentially planar [maximum deviation = 0.008 (1) Å for the N atom] and is oriented at a dihedral angle of 59.1 (1)° with respect to the benzene ring. In the crystal, pairs of C—H⋯O hydrogen bonds link centrosymmetrically related molecules into dimers, generating R (2) (2)(18) ring motifs. The crystal packing is further stabilized by C—H⋯π and C—O⋯π [O⋯centroid = 3.412 (2) Å and C—O⋯centroid = 115.0 (1)°] interactions. International Union of Crystallography 2011-12-17 /pmc/articles/PMC3254499/ /pubmed/22259442 http://dx.doi.org/10.1107/S1600536811053682 Text en © Vijayakumar et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Vijayakumar, S. Murugavel, S. Kannan, D. Bakthadoss, M. Methyl (Z)-2-[(2,4-dioxothiazolidin-3-yl)methyl]-3-(2-methylphenyl)prop-2-enoate |
title | Methyl (Z)-2-[(2,4-dioxothiazolidin-3-yl)methyl]-3-(2-methylphenyl)prop-2-enoate |
title_full | Methyl (Z)-2-[(2,4-dioxothiazolidin-3-yl)methyl]-3-(2-methylphenyl)prop-2-enoate |
title_fullStr | Methyl (Z)-2-[(2,4-dioxothiazolidin-3-yl)methyl]-3-(2-methylphenyl)prop-2-enoate |
title_full_unstemmed | Methyl (Z)-2-[(2,4-dioxothiazolidin-3-yl)methyl]-3-(2-methylphenyl)prop-2-enoate |
title_short | Methyl (Z)-2-[(2,4-dioxothiazolidin-3-yl)methyl]-3-(2-methylphenyl)prop-2-enoate |
title_sort | methyl (z)-2-[(2,4-dioxothiazolidin-3-yl)methyl]-3-(2-methylphenyl)prop-2-enoate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254499/ https://www.ncbi.nlm.nih.gov/pubmed/22259442 http://dx.doi.org/10.1107/S1600536811053682 |
work_keys_str_mv | AT vijayakumars methylz224dioxothiazolidin3ylmethyl32methylphenylprop2enoate AT murugavels methylz224dioxothiazolidin3ylmethyl32methylphenylprop2enoate AT kannand methylz224dioxothiazolidin3ylmethyl32methylphenylprop2enoate AT bakthadossm methylz224dioxothiazolidin3ylmethyl32methylphenylprop2enoate |