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2,2′-[Imidazolidine-1,3-diylbis(methyl­ene)]diphenol

In the title mol­ecule, C(17)H(20)N(2)O(2), the imidazolidine ring adopts a twist conformation. The mean plane through the five atoms of the imidazolidine ring makes dihedral angles of 70.18 (4) and 74.14 (4)° with the planes of the two aromatic rings. The dihedral angle between the benzene rings is...

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Detalles Bibliográficos
Autores principales: Rivera, Augusto, Nerio, Luz Stella, Ríos-Motta, Jaime, Fejfarová, Karla, Dušek, Michal
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254510/
https://www.ncbi.nlm.nih.gov/pubmed/22259455
http://dx.doi.org/10.1107/S1600536811053748
Descripción
Sumario:In the title mol­ecule, C(17)H(20)N(2)O(2), the imidazolidine ring adopts a twist conformation. The mean plane through the five atoms of the imidazolidine ring makes dihedral angles of 70.18 (4) and 74.14 (4)° with the planes of the two aromatic rings. The dihedral angle between the benzene rings is 53.11 (5)°. Both phenol –OH groups form intra­molecular hydrogen bonds to the N atoms, with graph-set motif S(6). In the crystal, pairs of O—H⋯O hydrogen bonds link the mol­ecules into dimers with R (4) (4)(18) ring motifs. The crystal packing is further stabilized by C—H⋯O and weak C—H⋯π inter­actions.