(S)-Methyl 2-benzamido-3-(3,4-dimeth­oxy­phen­yl)propano­ate

The dimethoxypbenzene ring in the title compound, C(19)H(21)NO(5), is gauche to the amide group and anti to the ester group. The chirality was confirmed to be S from two-dimensional NMR spectroscopy. In the crystal, N—H⋯O and C—H⋯O hydrogen bonds and several short-contact inter­actions (2.07–3.45 Å)...

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Detalles Bibliográficos
Autores principales: Naicker, Tricia, Govender, Thavendran, Kruger, Hendrick. G., Maguire, Glenn E. M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254516/
https://www.ncbi.nlm.nih.gov/pubmed/22259461
http://dx.doi.org/10.1107/S1600536811052767
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author Naicker, Tricia
Govender, Thavendran
Kruger, Hendrick. G.
Maguire, Glenn E. M.
author_facet Naicker, Tricia
Govender, Thavendran
Kruger, Hendrick. G.
Maguire, Glenn E. M.
author_sort Naicker, Tricia
collection PubMed
description The dimethoxypbenzene ring in the title compound, C(19)H(21)NO(5), is gauche to the amide group and anti to the ester group. The chirality was confirmed to be S from two-dimensional NMR spectroscopy. In the crystal, N—H⋯O and C—H⋯O hydrogen bonds and several short-contact inter­actions (2.07–3.45 Å) create chains parallel to [110]. The phenyl ring is disordered over two orientations in a 0.54 (2):0.46 (2) ratio.
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spelling pubmed-32545162012-01-18 (S)-Methyl 2-benzamido-3-(3,4-dimeth­oxy­phen­yl)propano­ate Naicker, Tricia Govender, Thavendran Kruger, Hendrick. G. Maguire, Glenn E. M. Acta Crystallogr Sect E Struct Rep Online Organic Papers The dimethoxypbenzene ring in the title compound, C(19)H(21)NO(5), is gauche to the amide group and anti to the ester group. The chirality was confirmed to be S from two-dimensional NMR spectroscopy. In the crystal, N—H⋯O and C—H⋯O hydrogen bonds and several short-contact inter­actions (2.07–3.45 Å) create chains parallel to [110]. The phenyl ring is disordered over two orientations in a 0.54 (2):0.46 (2) ratio. International Union of Crystallography 2011-12-21 /pmc/articles/PMC3254516/ /pubmed/22259461 http://dx.doi.org/10.1107/S1600536811052767 Text en © Naicker et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Naicker, Tricia
Govender, Thavendran
Kruger, Hendrick. G.
Maguire, Glenn E. M.
(S)-Methyl 2-benzamido-3-(3,4-dimeth­oxy­phen­yl)propano­ate
title (S)-Methyl 2-benzamido-3-(3,4-dimeth­oxy­phen­yl)propano­ate
title_full (S)-Methyl 2-benzamido-3-(3,4-dimeth­oxy­phen­yl)propano­ate
title_fullStr (S)-Methyl 2-benzamido-3-(3,4-dimeth­oxy­phen­yl)propano­ate
title_full_unstemmed (S)-Methyl 2-benzamido-3-(3,4-dimeth­oxy­phen­yl)propano­ate
title_short (S)-Methyl 2-benzamido-3-(3,4-dimeth­oxy­phen­yl)propano­ate
title_sort (s)-methyl 2-benzamido-3-(3,4-dimeth­oxy­phen­yl)propano­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254516/
https://www.ncbi.nlm.nih.gov/pubmed/22259461
http://dx.doi.org/10.1107/S1600536811052767
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