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5-(3,4-Dimeth­oxy­benzyl­idene)-1,3-dimethyl-1,3-diazinane-2,4,6-trione

In the title compound, C(15)H(16)N(2)O(5), the dihedral angle between 1,3-diazinane and benzene rings is only 4.27 (1)°. The essentially planar mol­ecular structure is characterized by a short intra­molecular C—H⋯O separation and by an exceptionally large bond angle of 138.25 (14)° at the bridging m...

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Detalles Bibliográficos
Autores principales: Gohain, Mukut, Muller, Theunis J., Bezuidenhoudt, Barend C. B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254518/
https://www.ncbi.nlm.nih.gov/pubmed/22259463
http://dx.doi.org/10.1107/S1600536811052986
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author Gohain, Mukut
Muller, Theunis J.
Bezuidenhoudt, Barend C. B.
author_facet Gohain, Mukut
Muller, Theunis J.
Bezuidenhoudt, Barend C. B.
author_sort Gohain, Mukut
collection PubMed
description In the title compound, C(15)H(16)N(2)O(5), the dihedral angle between 1,3-diazinane and benzene rings is only 4.27 (1)°. The essentially planar mol­ecular structure is characterized by a short intra­molecular C—H⋯O separation and by an exceptionally large bond angle of 138.25 (14)° at the bridging methine C atom. The meth­oxy groups deviate somewhat from the plane of the benzene ring, with C—C—O—C torsion angles of −15.6 (1) and 9.17 (6)°. In the crystal, mol­ecules form centrosymmetric dimers via donor–acceptor π–π inter­actions, with a centroid–centroid distance of 3.401 (1) Å.
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spelling pubmed-32545182012-01-18 5-(3,4-Dimeth­oxy­benzyl­idene)-1,3-dimethyl-1,3-diazinane-2,4,6-trione Gohain, Mukut Muller, Theunis J. Bezuidenhoudt, Barend C. B. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(15)H(16)N(2)O(5), the dihedral angle between 1,3-diazinane and benzene rings is only 4.27 (1)°. The essentially planar mol­ecular structure is characterized by a short intra­molecular C—H⋯O separation and by an exceptionally large bond angle of 138.25 (14)° at the bridging methine C atom. The meth­oxy groups deviate somewhat from the plane of the benzene ring, with C—C—O—C torsion angles of −15.6 (1) and 9.17 (6)°. In the crystal, mol­ecules form centrosymmetric dimers via donor–acceptor π–π inter­actions, with a centroid–centroid distance of 3.401 (1) Å. International Union of Crystallography 2011-12-21 /pmc/articles/PMC3254518/ /pubmed/22259463 http://dx.doi.org/10.1107/S1600536811052986 Text en © Gohain et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gohain, Mukut
Muller, Theunis J.
Bezuidenhoudt, Barend C. B.
5-(3,4-Dimeth­oxy­benzyl­idene)-1,3-dimethyl-1,3-diazinane-2,4,6-trione
title 5-(3,4-Dimeth­oxy­benzyl­idene)-1,3-dimethyl-1,3-diazinane-2,4,6-trione
title_full 5-(3,4-Dimeth­oxy­benzyl­idene)-1,3-dimethyl-1,3-diazinane-2,4,6-trione
title_fullStr 5-(3,4-Dimeth­oxy­benzyl­idene)-1,3-dimethyl-1,3-diazinane-2,4,6-trione
title_full_unstemmed 5-(3,4-Dimeth­oxy­benzyl­idene)-1,3-dimethyl-1,3-diazinane-2,4,6-trione
title_short 5-(3,4-Dimeth­oxy­benzyl­idene)-1,3-dimethyl-1,3-diazinane-2,4,6-trione
title_sort 5-(3,4-dimeth­oxy­benzyl­idene)-1,3-dimethyl-1,3-diazinane-2,4,6-trione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254518/
https://www.ncbi.nlm.nih.gov/pubmed/22259463
http://dx.doi.org/10.1107/S1600536811052986
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