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4-Isopropyl­amino-3-nitro­benzonitrile

In the title compound, C(10)H(11)N(3)O(2), the nitro group is essentially coplanar with the aromatic ring [dihedral angle = 3.4 (3)°] and forms an intra­molecular N—H⋯O hydrogen bond with the amine group. In the crystal, weak aromatic C—H⋯O and C—H⋯N hydrogen bonds link the mol­ecules. Weak aromatic...

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Autor principal: Jia, Hong-sheng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254521/
https://www.ncbi.nlm.nih.gov/pubmed/22259467
http://dx.doi.org/10.1107/S1600536811051737
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author Jia, Hong-sheng
author_facet Jia, Hong-sheng
author_sort Jia, Hong-sheng
collection PubMed
description In the title compound, C(10)H(11)N(3)O(2), the nitro group is essentially coplanar with the aromatic ring [dihedral angle = 3.4 (3)°] and forms an intra­molecular N—H⋯O hydrogen bond with the amine group. In the crystal, weak aromatic C—H⋯O and C—H⋯N hydrogen bonds link the mol­ecules. Weak aromatic ring π–π inter­actions [minimum ring centroid–centroid separation = 3.9841 (16) Å] are also present.
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spelling pubmed-32545212012-01-18 4-Isopropyl­amino-3-nitro­benzonitrile Jia, Hong-sheng Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(10)H(11)N(3)O(2), the nitro group is essentially coplanar with the aromatic ring [dihedral angle = 3.4 (3)°] and forms an intra­molecular N—H⋯O hydrogen bond with the amine group. In the crystal, weak aromatic C—H⋯O and C—H⋯N hydrogen bonds link the mol­ecules. Weak aromatic ring π–π inter­actions [minimum ring centroid–centroid separation = 3.9841 (16) Å] are also present. International Union of Crystallography 2011-12-21 /pmc/articles/PMC3254521/ /pubmed/22259467 http://dx.doi.org/10.1107/S1600536811051737 Text en © Hong-sheng Jia 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Jia, Hong-sheng
4-Isopropyl­amino-3-nitro­benzonitrile
title 4-Isopropyl­amino-3-nitro­benzonitrile
title_full 4-Isopropyl­amino-3-nitro­benzonitrile
title_fullStr 4-Isopropyl­amino-3-nitro­benzonitrile
title_full_unstemmed 4-Isopropyl­amino-3-nitro­benzonitrile
title_short 4-Isopropyl­amino-3-nitro­benzonitrile
title_sort 4-isopropyl­amino-3-nitro­benzonitrile
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254521/
https://www.ncbi.nlm.nih.gov/pubmed/22259467
http://dx.doi.org/10.1107/S1600536811051737
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