4-Methyl­anilinium perchlorate 18-crown-6 clathrate

In the title compound, C(7)H(10)N(+)·ClO(4) (−)·C(12)H(24)O(6), the 4-methyl­anilinium cation inter­acts with an 18-crown-6 mol­ecule forming a rotator–stator-like structure through bifurcated N—H⋯(O,O) hydrogen bonds between the ammonium group of the cation and the O atoms of the crown ether mol­ec...

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Detalles Bibliográficos
Autor principal: Wang, Yu-Feng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254523/
https://www.ncbi.nlm.nih.gov/pubmed/22259469
http://dx.doi.org/10.1107/S1600536811053992
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author Wang, Yu-Feng
author_facet Wang, Yu-Feng
author_sort Wang, Yu-Feng
collection PubMed
description In the title compound, C(7)H(10)N(+)·ClO(4) (−)·C(12)H(24)O(6), the 4-methyl­anilinium cation inter­acts with an 18-crown-6 mol­ecule forming a rotator–stator-like structure through bifurcated N—H⋯(O,O) hydrogen bonds between the ammonium group of the cation and the O atoms of the crown ether mol­ecule. All three components of the structure possess mirror symmetry. The benzene ring is inclined to the mean plane of the crown ether molecule by 86.84 (8)°.
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spelling pubmed-32545232012-01-18 4-Methyl­anilinium perchlorate 18-crown-6 clathrate Wang, Yu-Feng Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(7)H(10)N(+)·ClO(4) (−)·C(12)H(24)O(6), the 4-methyl­anilinium cation inter­acts with an 18-crown-6 mol­ecule forming a rotator–stator-like structure through bifurcated N—H⋯(O,O) hydrogen bonds between the ammonium group of the cation and the O atoms of the crown ether mol­ecule. All three components of the structure possess mirror symmetry. The benzene ring is inclined to the mean plane of the crown ether molecule by 86.84 (8)°. International Union of Crystallography 2011-12-21 /pmc/articles/PMC3254523/ /pubmed/22259469 http://dx.doi.org/10.1107/S1600536811053992 Text en © Yu-Feng Wang 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Wang, Yu-Feng
4-Methyl­anilinium perchlorate 18-crown-6 clathrate
title 4-Methyl­anilinium perchlorate 18-crown-6 clathrate
title_full 4-Methyl­anilinium perchlorate 18-crown-6 clathrate
title_fullStr 4-Methyl­anilinium perchlorate 18-crown-6 clathrate
title_full_unstemmed 4-Methyl­anilinium perchlorate 18-crown-6 clathrate
title_short 4-Methyl­anilinium perchlorate 18-crown-6 clathrate
title_sort 4-methyl­anilinium perchlorate 18-crown-6 clathrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254523/
https://www.ncbi.nlm.nih.gov/pubmed/22259469
http://dx.doi.org/10.1107/S1600536811053992
work_keys_str_mv AT wangyufeng 4methylaniliniumperchlorate18crown6clathrate

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