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2-[((E)-2-{2-[(E)-2-Hy­droxy­benzyl­idene]hydrazinecarbon­yl}hydrazinyl­idene)meth­yl]phenol

The mol­ecule of the title compound, C(15)H(14)N(4)O(3), is completed by the application of crystallographic twofold symmetry, with the carbonyl group lying on the rotation axis. The mol­ecule is close to planar: the greatest deviation of a torsion angle from 0° is 7.3 (2)° about the bond linking th...

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Detalles Bibliográficos
Autores principales: Bikas, Rahman, Anarjan, Parisa Mahboubi, Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254530/
https://www.ncbi.nlm.nih.gov/pubmed/22259476
http://dx.doi.org/10.1107/S1600536811053268
Descripción
Sumario:The mol­ecule of the title compound, C(15)H(14)N(4)O(3), is completed by the application of crystallographic twofold symmetry, with the carbonyl group lying on the rotation axis. The mol­ecule is close to planar: the greatest deviation of a torsion angle from 0° is 7.3 (2)° about the bond linking the phenol ring to the rest of the mol­ecule. An intra­molecular O—H⋯N(imine) hydrogen bond is formed in each half of the mol­ecule. The carbonyl O atom is anti with respect to the amine H atoms and this allows for the formation of N—H⋯O(hydrox­yl) hydrogen bonds in the crystal, which results in supra­molecular layers lying parallel to (100).