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2-[((E)-2-{2-[(E)-2-Hy­droxy­benzyl­idene]hydrazinecarbon­yl}hydrazinyl­idene)meth­yl]phenol

The mol­ecule of the title compound, C(15)H(14)N(4)O(3), is completed by the application of crystallographic twofold symmetry, with the carbonyl group lying on the rotation axis. The mol­ecule is close to planar: the greatest deviation of a torsion angle from 0° is 7.3 (2)° about the bond linking th...

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Autores principales: Bikas, Rahman, Anarjan, Parisa Mahboubi, Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254530/
https://www.ncbi.nlm.nih.gov/pubmed/22259476
http://dx.doi.org/10.1107/S1600536811053268
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author Bikas, Rahman
Anarjan, Parisa Mahboubi
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Bikas, Rahman
Anarjan, Parisa Mahboubi
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Bikas, Rahman
collection PubMed
description The mol­ecule of the title compound, C(15)H(14)N(4)O(3), is completed by the application of crystallographic twofold symmetry, with the carbonyl group lying on the rotation axis. The mol­ecule is close to planar: the greatest deviation of a torsion angle from 0° is 7.3 (2)° about the bond linking the phenol ring to the rest of the mol­ecule. An intra­molecular O—H⋯N(imine) hydrogen bond is formed in each half of the mol­ecule. The carbonyl O atom is anti with respect to the amine H atoms and this allows for the formation of N—H⋯O(hydrox­yl) hydrogen bonds in the crystal, which results in supra­molecular layers lying parallel to (100).
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spelling pubmed-32545302012-01-18 2-[((E)-2-{2-[(E)-2-Hy­droxy­benzyl­idene]hydrazinecarbon­yl}hydrazinyl­idene)meth­yl]phenol Bikas, Rahman Anarjan, Parisa Mahboubi Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title compound, C(15)H(14)N(4)O(3), is completed by the application of crystallographic twofold symmetry, with the carbonyl group lying on the rotation axis. The mol­ecule is close to planar: the greatest deviation of a torsion angle from 0° is 7.3 (2)° about the bond linking the phenol ring to the rest of the mol­ecule. An intra­molecular O—H⋯N(imine) hydrogen bond is formed in each half of the mol­ecule. The carbonyl O atom is anti with respect to the amine H atoms and this allows for the formation of N—H⋯O(hydrox­yl) hydrogen bonds in the crystal, which results in supra­molecular layers lying parallel to (100). International Union of Crystallography 2011-12-21 /pmc/articles/PMC3254530/ /pubmed/22259476 http://dx.doi.org/10.1107/S1600536811053268 Text en © Bikas et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Bikas, Rahman
Anarjan, Parisa Mahboubi
Ng, Seik Weng
Tiekink, Edward R. T.
2-[((E)-2-{2-[(E)-2-Hy­droxy­benzyl­idene]hydrazinecarbon­yl}hydrazinyl­idene)meth­yl]phenol
title 2-[((E)-2-{2-[(E)-2-Hy­droxy­benzyl­idene]hydrazinecarbon­yl}hydrazinyl­idene)meth­yl]phenol
title_full 2-[((E)-2-{2-[(E)-2-Hy­droxy­benzyl­idene]hydrazinecarbon­yl}hydrazinyl­idene)meth­yl]phenol
title_fullStr 2-[((E)-2-{2-[(E)-2-Hy­droxy­benzyl­idene]hydrazinecarbon­yl}hydrazinyl­idene)meth­yl]phenol
title_full_unstemmed 2-[((E)-2-{2-[(E)-2-Hy­droxy­benzyl­idene]hydrazinecarbon­yl}hydrazinyl­idene)meth­yl]phenol
title_short 2-[((E)-2-{2-[(E)-2-Hy­droxy­benzyl­idene]hydrazinecarbon­yl}hydrazinyl­idene)meth­yl]phenol
title_sort 2-[((e)-2-{2-[(e)-2-hy­droxy­benzyl­idene]hydrazinecarbon­yl}hydrazinyl­idene)meth­yl]phenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254530/
https://www.ncbi.nlm.nih.gov/pubmed/22259476
http://dx.doi.org/10.1107/S1600536811053268
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