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2-[((E)-2-{2-[(E)-2-Hydroxybenzylidene]hydrazinecarbonyl}hydrazinylidene)methyl]phenol
The molecule of the title compound, C(15)H(14)N(4)O(3), is completed by the application of crystallographic twofold symmetry, with the carbonyl group lying on the rotation axis. The molecule is close to planar: the greatest deviation of a torsion angle from 0° is 7.3 (2)° about the bond linking th...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254530/ https://www.ncbi.nlm.nih.gov/pubmed/22259476 http://dx.doi.org/10.1107/S1600536811053268 |
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author | Bikas, Rahman Anarjan, Parisa Mahboubi Ng, Seik Weng Tiekink, Edward R. T. |
author_facet | Bikas, Rahman Anarjan, Parisa Mahboubi Ng, Seik Weng Tiekink, Edward R. T. |
author_sort | Bikas, Rahman |
collection | PubMed |
description | The molecule of the title compound, C(15)H(14)N(4)O(3), is completed by the application of crystallographic twofold symmetry, with the carbonyl group lying on the rotation axis. The molecule is close to planar: the greatest deviation of a torsion angle from 0° is 7.3 (2)° about the bond linking the phenol ring to the rest of the molecule. An intramolecular O—H⋯N(imine) hydrogen bond is formed in each half of the molecule. The carbonyl O atom is anti with respect to the amine H atoms and this allows for the formation of N—H⋯O(hydroxyl) hydrogen bonds in the crystal, which results in supramolecular layers lying parallel to (100). |
format | Online Article Text |
id | pubmed-3254530 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32545302012-01-18 2-[((E)-2-{2-[(E)-2-Hydroxybenzylidene]hydrazinecarbonyl}hydrazinylidene)methyl]phenol Bikas, Rahman Anarjan, Parisa Mahboubi Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers The molecule of the title compound, C(15)H(14)N(4)O(3), is completed by the application of crystallographic twofold symmetry, with the carbonyl group lying on the rotation axis. The molecule is close to planar: the greatest deviation of a torsion angle from 0° is 7.3 (2)° about the bond linking the phenol ring to the rest of the molecule. An intramolecular O—H⋯N(imine) hydrogen bond is formed in each half of the molecule. The carbonyl O atom is anti with respect to the amine H atoms and this allows for the formation of N—H⋯O(hydroxyl) hydrogen bonds in the crystal, which results in supramolecular layers lying parallel to (100). International Union of Crystallography 2011-12-21 /pmc/articles/PMC3254530/ /pubmed/22259476 http://dx.doi.org/10.1107/S1600536811053268 Text en © Bikas et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Bikas, Rahman Anarjan, Parisa Mahboubi Ng, Seik Weng Tiekink, Edward R. T. 2-[((E)-2-{2-[(E)-2-Hydroxybenzylidene]hydrazinecarbonyl}hydrazinylidene)methyl]phenol |
title | 2-[((E)-2-{2-[(E)-2-Hydroxybenzylidene]hydrazinecarbonyl}hydrazinylidene)methyl]phenol |
title_full | 2-[((E)-2-{2-[(E)-2-Hydroxybenzylidene]hydrazinecarbonyl}hydrazinylidene)methyl]phenol |
title_fullStr | 2-[((E)-2-{2-[(E)-2-Hydroxybenzylidene]hydrazinecarbonyl}hydrazinylidene)methyl]phenol |
title_full_unstemmed | 2-[((E)-2-{2-[(E)-2-Hydroxybenzylidene]hydrazinecarbonyl}hydrazinylidene)methyl]phenol |
title_short | 2-[((E)-2-{2-[(E)-2-Hydroxybenzylidene]hydrazinecarbonyl}hydrazinylidene)methyl]phenol |
title_sort | 2-[((e)-2-{2-[(e)-2-hydroxybenzylidene]hydrazinecarbonyl}hydrazinylidene)methyl]phenol |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254530/ https://www.ncbi.nlm.nih.gov/pubmed/22259476 http://dx.doi.org/10.1107/S1600536811053268 |
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