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Acridin-10-ium 6-carboxypyridine-2-carboxylate
The title compound, C(13)H(10)N(+)·C(7)H(4)NO(4) (−), consists of a protonated acridinium cation and a 6-carboxypyridine-2-carboxylate monoanion. The carboxylate group of the anion appears to be delocalized on the basis of the nearly equivalent C—O bond lengths. In the crystal, the anions are co...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254532/ https://www.ncbi.nlm.nih.gov/pubmed/22259478 http://dx.doi.org/10.1107/S1600536811053578 |
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author | Ha, Kwang |
author_facet | Ha, Kwang |
author_sort | Ha, Kwang |
collection | PubMed |
description | The title compound, C(13)H(10)N(+)·C(7)H(4)NO(4) (−), consists of a protonated acridinium cation and a 6-carboxypyridine-2-carboxylate monoanion. The carboxylate group of the anion appears to be delocalized on the basis of the nearly equivalent C—O bond lengths. In the crystal, the anions are connected by strong O—H⋯O hydrogen bonds, forming chains along the b axis. The acridinium cations are linked to the anionic chains by strong N—H⋯O hydrogen bonds between the carboxylate group of the anion and the N—H group of the cation. Along the b axis, successive chains stack in opposite directions. Weak intermolecular C—H⋯O hydrogen bonds further stabilize the crystal structure. |
format | Online Article Text |
id | pubmed-3254532 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32545322012-01-18 Acridin-10-ium 6-carboxypyridine-2-carboxylate Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(13)H(10)N(+)·C(7)H(4)NO(4) (−), consists of a protonated acridinium cation and a 6-carboxypyridine-2-carboxylate monoanion. The carboxylate group of the anion appears to be delocalized on the basis of the nearly equivalent C—O bond lengths. In the crystal, the anions are connected by strong O—H⋯O hydrogen bonds, forming chains along the b axis. The acridinium cations are linked to the anionic chains by strong N—H⋯O hydrogen bonds between the carboxylate group of the anion and the N—H group of the cation. Along the b axis, successive chains stack in opposite directions. Weak intermolecular C—H⋯O hydrogen bonds further stabilize the crystal structure. International Union of Crystallography 2011-12-21 /pmc/articles/PMC3254532/ /pubmed/22259478 http://dx.doi.org/10.1107/S1600536811053578 Text en © Kwang Ha 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Ha, Kwang Acridin-10-ium 6-carboxypyridine-2-carboxylate |
title | Acridin-10-ium 6-carboxypyridine-2-carboxylate |
title_full | Acridin-10-ium 6-carboxypyridine-2-carboxylate |
title_fullStr | Acridin-10-ium 6-carboxypyridine-2-carboxylate |
title_full_unstemmed | Acridin-10-ium 6-carboxypyridine-2-carboxylate |
title_short | Acridin-10-ium 6-carboxypyridine-2-carboxylate |
title_sort | acridin-10-ium 6-carboxypyridine-2-carboxylate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254532/ https://www.ncbi.nlm.nih.gov/pubmed/22259478 http://dx.doi.org/10.1107/S1600536811053578 |
work_keys_str_mv | AT hakwang acridin10ium6carboxypyridine2carboxylate |