Cargando…

Acridin-10-ium 6-carb­oxy­pyridine-2-carboxyl­ate

The title compound, C(13)H(10)N(+)·C(7)H(4)NO(4) (−), consists of a protonated acridinium cation and a 6-carb­oxy­pyridine-2-carboxyl­ate monoanion. The carboxyl­ate group of the anion appears to be delocalized on the basis of the nearly equivalent C—O bond lengths. In the crystal, the anions are co...

Descripción completa

Detalles Bibliográficos
Autor principal: Ha, Kwang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254532/
https://www.ncbi.nlm.nih.gov/pubmed/22259478
http://dx.doi.org/10.1107/S1600536811053578
_version_ 1782220875346477056
author Ha, Kwang
author_facet Ha, Kwang
author_sort Ha, Kwang
collection PubMed
description The title compound, C(13)H(10)N(+)·C(7)H(4)NO(4) (−), consists of a protonated acridinium cation and a 6-carb­oxy­pyridine-2-carboxyl­ate monoanion. The carboxyl­ate group of the anion appears to be delocalized on the basis of the nearly equivalent C—O bond lengths. In the crystal, the anions are connected by strong O—H⋯O hydrogen bonds, forming chains along the b axis. The acridinium cations are linked to the anionic chains by strong N—H⋯O hydrogen bonds between the carboxyl­ate group of the anion and the N—H group of the cation. Along the b axis, successive chains stack in opposite directions. Weak inter­molecular C—H⋯O hydrogen bonds further stabilize the crystal structure.
format Online
Article
Text
id pubmed-3254532
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32545322012-01-18 Acridin-10-ium 6-carb­oxy­pyridine-2-carboxyl­ate Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(13)H(10)N(+)·C(7)H(4)NO(4) (−), consists of a protonated acridinium cation and a 6-carb­oxy­pyridine-2-carboxyl­ate monoanion. The carboxyl­ate group of the anion appears to be delocalized on the basis of the nearly equivalent C—O bond lengths. In the crystal, the anions are connected by strong O—H⋯O hydrogen bonds, forming chains along the b axis. The acridinium cations are linked to the anionic chains by strong N—H⋯O hydrogen bonds between the carboxyl­ate group of the anion and the N—H group of the cation. Along the b axis, successive chains stack in opposite directions. Weak inter­molecular C—H⋯O hydrogen bonds further stabilize the crystal structure. International Union of Crystallography 2011-12-21 /pmc/articles/PMC3254532/ /pubmed/22259478 http://dx.doi.org/10.1107/S1600536811053578 Text en © Kwang Ha 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ha, Kwang
Acridin-10-ium 6-carb­oxy­pyridine-2-carboxyl­ate
title Acridin-10-ium 6-carb­oxy­pyridine-2-carboxyl­ate
title_full Acridin-10-ium 6-carb­oxy­pyridine-2-carboxyl­ate
title_fullStr Acridin-10-ium 6-carb­oxy­pyridine-2-carboxyl­ate
title_full_unstemmed Acridin-10-ium 6-carb­oxy­pyridine-2-carboxyl­ate
title_short Acridin-10-ium 6-carb­oxy­pyridine-2-carboxyl­ate
title_sort acridin-10-ium 6-carb­oxy­pyridine-2-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254532/
https://www.ncbi.nlm.nih.gov/pubmed/22259478
http://dx.doi.org/10.1107/S1600536811053578
work_keys_str_mv AT hakwang acridin10ium6carboxypyridine2carboxylate