Ethyl 1-(2-hy­droxy­eth­yl)-2-[2-(methyl­sulfan­yl)eth­yl]-1H-benzimidazole-5-carboxyl­ate

In the crystal structure of the title compound, C(15)H(20)N(2)O(3)S, the hy­droxy group is involved in the formation of O—H⋯N hydrogen bonds, which link two mol­ecules into a centrosymmetric dimer. Weak C—H⋯O hydrogen bonds further link these dimers into chains propagating along the a axis. The crys...

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Autores principales: Hamzah, Nurasyikin, Ngah, Nurziana, Abd Hamid, Shafida, Abdul Rahim, Aisyah Saad
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254533/
https://www.ncbi.nlm.nih.gov/pubmed/22259479
http://dx.doi.org/10.1107/S160053681105389X
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author Hamzah, Nurasyikin
Ngah, Nurziana
Abd Hamid, Shafida
Abdul Rahim, Aisyah Saad
author_facet Hamzah, Nurasyikin
Ngah, Nurziana
Abd Hamid, Shafida
Abdul Rahim, Aisyah Saad
author_sort Hamzah, Nurasyikin
collection PubMed
description In the crystal structure of the title compound, C(15)H(20)N(2)O(3)S, the hy­droxy group is involved in the formation of O—H⋯N hydrogen bonds, which link two mol­ecules into a centrosymmetric dimer. Weak C—H⋯O hydrogen bonds further link these dimers into chains propagating along the a axis. The crystal packing exhibits π–π inter­actions between the five- and six-membered rings of neighbouring mol­ecules [centroid–centroid distance = 3.819 (2) Å] and short inter­molecular S⋯S contacts of 3.495 (1) Å.
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spelling pubmed-32545332012-01-18 Ethyl 1-(2-hy­droxy­eth­yl)-2-[2-(methyl­sulfan­yl)eth­yl]-1H-benzimidazole-5-carboxyl­ate Hamzah, Nurasyikin Ngah, Nurziana Abd Hamid, Shafida Abdul Rahim, Aisyah Saad Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, C(15)H(20)N(2)O(3)S, the hy­droxy group is involved in the formation of O—H⋯N hydrogen bonds, which link two mol­ecules into a centrosymmetric dimer. Weak C—H⋯O hydrogen bonds further link these dimers into chains propagating along the a axis. The crystal packing exhibits π–π inter­actions between the five- and six-membered rings of neighbouring mol­ecules [centroid–centroid distance = 3.819 (2) Å] and short inter­molecular S⋯S contacts of 3.495 (1) Å. International Union of Crystallography 2011-12-21 /pmc/articles/PMC3254533/ /pubmed/22259479 http://dx.doi.org/10.1107/S160053681105389X Text en © Hamzah et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Hamzah, Nurasyikin
Ngah, Nurziana
Abd Hamid, Shafida
Abdul Rahim, Aisyah Saad
Ethyl 1-(2-hy­droxy­eth­yl)-2-[2-(methyl­sulfan­yl)eth­yl]-1H-benzimidazole-5-carboxyl­ate
title Ethyl 1-(2-hy­droxy­eth­yl)-2-[2-(methyl­sulfan­yl)eth­yl]-1H-benzimidazole-5-carboxyl­ate
title_full Ethyl 1-(2-hy­droxy­eth­yl)-2-[2-(methyl­sulfan­yl)eth­yl]-1H-benzimidazole-5-carboxyl­ate
title_fullStr Ethyl 1-(2-hy­droxy­eth­yl)-2-[2-(methyl­sulfan­yl)eth­yl]-1H-benzimidazole-5-carboxyl­ate
title_full_unstemmed Ethyl 1-(2-hy­droxy­eth­yl)-2-[2-(methyl­sulfan­yl)eth­yl]-1H-benzimidazole-5-carboxyl­ate
title_short Ethyl 1-(2-hy­droxy­eth­yl)-2-[2-(methyl­sulfan­yl)eth­yl]-1H-benzimidazole-5-carboxyl­ate
title_sort ethyl 1-(2-hy­droxy­eth­yl)-2-[2-(methyl­sulfan­yl)eth­yl]-1h-benzimidazole-5-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254533/
https://www.ncbi.nlm.nih.gov/pubmed/22259479
http://dx.doi.org/10.1107/S160053681105389X
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AT abdulrahimaisyahsaad ethyl12hydroxyethyl22methylsulfanylethyl1hbenzimidazole5carboxylate

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