3a,11b-Dihy­droxy-3a,11b-dihydro-1H-imidazo[4,5-f][1,10]phenanthroline-2(3H)-thione

The title compound, C(13)H(10)N(4)O(2)S, was prepared through a cyclization reaction of 1,10-phenanthroline-5,6-dione and thio­urea. The dihedral angle between the pyridine rings is 8.22 (2)°. In the crystal, mol­ecules are connected by N—H⋯O, O—H⋯N, N—H⋯S and O—H⋯S hydrogen bonds, forming a three-d...

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Detalles Bibliográficos
Autores principales: Wang, Hua, Mei, Peng, Chu, Wen-Yi, Sun, Zhi-Zhong, Hou, Yan-Jun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254542/
https://www.ncbi.nlm.nih.gov/pubmed/22259489
http://dx.doi.org/10.1107/S1600536811053967
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author Wang, Hua
Mei, Peng
Chu, Wen-Yi
Sun, Zhi-Zhong
Hou, Yan-Jun
author_facet Wang, Hua
Mei, Peng
Chu, Wen-Yi
Sun, Zhi-Zhong
Hou, Yan-Jun
author_sort Wang, Hua
collection PubMed
description The title compound, C(13)H(10)N(4)O(2)S, was prepared through a cyclization reaction of 1,10-phenanthroline-5,6-dione and thio­urea. The dihedral angle between the pyridine rings is 8.22 (2)°. In the crystal, mol­ecules are connected by N—H⋯O, O—H⋯N, N—H⋯S and O—H⋯S hydrogen bonds, forming a three-dimensional network.
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spelling pubmed-32545422012-01-18 3a,11b-Dihy­droxy-3a,11b-dihydro-1H-imidazo[4,5-f][1,10]phenanthroline-2(3H)-thione Wang, Hua Mei, Peng Chu, Wen-Yi Sun, Zhi-Zhong Hou, Yan-Jun Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(13)H(10)N(4)O(2)S, was prepared through a cyclization reaction of 1,10-phenanthroline-5,6-dione and thio­urea. The dihedral angle between the pyridine rings is 8.22 (2)°. In the crystal, mol­ecules are connected by N—H⋯O, O—H⋯N, N—H⋯S and O—H⋯S hydrogen bonds, forming a three-dimensional network. International Union of Crystallography 2011-12-21 /pmc/articles/PMC3254542/ /pubmed/22259489 http://dx.doi.org/10.1107/S1600536811053967 Text en © Wang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Wang, Hua
Mei, Peng
Chu, Wen-Yi
Sun, Zhi-Zhong
Hou, Yan-Jun
3a,11b-Dihy­droxy-3a,11b-dihydro-1H-imidazo[4,5-f][1,10]phenanthroline-2(3H)-thione
title 3a,11b-Dihy­droxy-3a,11b-dihydro-1H-imidazo[4,5-f][1,10]phenanthroline-2(3H)-thione
title_full 3a,11b-Dihy­droxy-3a,11b-dihydro-1H-imidazo[4,5-f][1,10]phenanthroline-2(3H)-thione
title_fullStr 3a,11b-Dihy­droxy-3a,11b-dihydro-1H-imidazo[4,5-f][1,10]phenanthroline-2(3H)-thione
title_full_unstemmed 3a,11b-Dihy­droxy-3a,11b-dihydro-1H-imidazo[4,5-f][1,10]phenanthroline-2(3H)-thione
title_short 3a,11b-Dihy­droxy-3a,11b-dihydro-1H-imidazo[4,5-f][1,10]phenanthroline-2(3H)-thione
title_sort 3a,11b-dihy­droxy-3a,11b-dihydro-1h-imidazo[4,5-f][1,10]phenanthroline-2(3h)-thione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254542/
https://www.ncbi.nlm.nih.gov/pubmed/22259489
http://dx.doi.org/10.1107/S1600536811053967
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