(E)-4-[(3,5-Dimethyl­phen­yl)imino­meth­yl]-2-meth­oxy-3-nitro­phenol

The mol­ecule of the title compound, C(16)H(16)N(2)O(4), exists in the E configuration with respect to the central C=N double bond. The dihedral angle between the two benzene rings is 2.17 (9) Å. In the crystal, mol­ecules are linked via O—H⋯N hydrogen bonds into chains that propagate along the b-ax...

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Detalles Bibliográficos
Autores principales: Yang, Zhong-Ming, Su, Deng-Cheng, Zhu, Hai-Liang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254553/
https://www.ncbi.nlm.nih.gov/pubmed/22259502
http://dx.doi.org/10.1107/S1600536811054407
Descripción
Sumario:The mol­ecule of the title compound, C(16)H(16)N(2)O(4), exists in the E configuration with respect to the central C=N double bond. The dihedral angle between the two benzene rings is 2.17 (9) Å. In the crystal, mol­ecules are linked via O—H⋯N hydrogen bonds into chains that propagate along the b-axis direction. There is also π–π stacking of inversion-related mol­ecules, with inter­planar spacings of 3.479 (5) Å and ring centroid–centroid distances of 3.876 (4) Å.

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