N-(2-Chloro-5-methyl­phen­yl)succinamic acid

In the title compound, C(11)H(12)ClNO(3), the conformation of the N—H bond in the amide segment is syn with respect to the ortho-Cl atom. The amide and carboxyl C=O groups are syn to each other. Furthermore, the C=O and O—H bonds of the carboxyl group are in syn positions with respect to each other....

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Detalles Bibliográficos
Autores principales: Gowda, B. Thimme, Foro, Sabine, Chaithanya, U.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254554/
https://www.ncbi.nlm.nih.gov/pubmed/22259503
http://dx.doi.org/10.1107/S1600536811054638
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author Gowda, B. Thimme
Foro, Sabine
Chaithanya, U.
author_facet Gowda, B. Thimme
Foro, Sabine
Chaithanya, U.
author_sort Gowda, B. Thimme
collection PubMed
description In the title compound, C(11)H(12)ClNO(3), the conformation of the N—H bond in the amide segment is syn with respect to the ortho-Cl atom. The amide and carboxyl C=O groups are syn to each other. Furthermore, the C=O and O—H bonds of the carboxyl group are in syn positions with respect to each other. The dihedral angle between the benzene ring and the amide group is 47.8 (2)°. In the crystal, mol­ecules are connected by pairs of O—H⋯O hydrogen bonds, forming inversion dimers. The dimers are further linked by N—H⋯O hydrogen bonds into double chains along the b-axis direction.
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spelling pubmed-32545542012-01-18 N-(2-Chloro-5-methyl­phen­yl)succinamic acid Gowda, B. Thimme Foro, Sabine Chaithanya, U. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(11)H(12)ClNO(3), the conformation of the N—H bond in the amide segment is syn with respect to the ortho-Cl atom. The amide and carboxyl C=O groups are syn to each other. Furthermore, the C=O and O—H bonds of the carboxyl group are in syn positions with respect to each other. The dihedral angle between the benzene ring and the amide group is 47.8 (2)°. In the crystal, mol­ecules are connected by pairs of O—H⋯O hydrogen bonds, forming inversion dimers. The dimers are further linked by N—H⋯O hydrogen bonds into double chains along the b-axis direction. International Union of Crystallography 2011-12-23 /pmc/articles/PMC3254554/ /pubmed/22259503 http://dx.doi.org/10.1107/S1600536811054638 Text en © Gowda et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gowda, B. Thimme
Foro, Sabine
Chaithanya, U.
N-(2-Chloro-5-methyl­phen­yl)succinamic acid
title N-(2-Chloro-5-methyl­phen­yl)succinamic acid
title_full N-(2-Chloro-5-methyl­phen­yl)succinamic acid
title_fullStr N-(2-Chloro-5-methyl­phen­yl)succinamic acid
title_full_unstemmed N-(2-Chloro-5-methyl­phen­yl)succinamic acid
title_short N-(2-Chloro-5-methyl­phen­yl)succinamic acid
title_sort n-(2-chloro-5-methyl­phen­yl)succinamic acid
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254554/
https://www.ncbi.nlm.nih.gov/pubmed/22259503
http://dx.doi.org/10.1107/S1600536811054638
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