N-(5-Sulfanyl­idene-4,5-dihydro-1,3,4-thia­diazol-2-yl)acetamide dimethyl sulfoxide disolvate

In the title compound, C(4)H(5)N(3)OS(2)·2C(2)H(6)OS, the five-membered heterocyclic ring and the N—(C=O)—C plane of the acetamide group are essentially co-planar, with a dihedral angle of 1.25 (3)°. Inter­molecular N—H⋯O hydrogen bonds between the acetamide compound and the dimethyl sulfoxide mol­e...

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Detalles Bibliográficos
Autores principales: Kang, Sung Kwon, Cho, Nam Sook, Jang, Siyoung
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254557/
https://www.ncbi.nlm.nih.gov/pubmed/22259506
http://dx.doi.org/10.1107/S1600536811054298
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author Kang, Sung Kwon
Cho, Nam Sook
Jang, Siyoung
author_facet Kang, Sung Kwon
Cho, Nam Sook
Jang, Siyoung
author_sort Kang, Sung Kwon
collection PubMed
description In the title compound, C(4)H(5)N(3)OS(2)·2C(2)H(6)OS, the five-membered heterocyclic ring and the N—(C=O)—C plane of the acetamide group are essentially co-planar, with a dihedral angle of 1.25 (3)°. Inter­molecular N—H⋯O hydrogen bonds between the acetamide compound and the dimethyl sulfoxide mol­ecules stabilize the crystal structure. The two dimethyl sulfoxide mol­ecules are each disordered over two positions with occupancy ratios of 0.605 (2):0.395 (2) and 0.8629 (18):0.1371 (18).
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spelling pubmed-32545572012-01-18 N-(5-Sulfanyl­idene-4,5-dihydro-1,3,4-thia­diazol-2-yl)acetamide dimethyl sulfoxide disolvate Kang, Sung Kwon Cho, Nam Sook Jang, Siyoung Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(4)H(5)N(3)OS(2)·2C(2)H(6)OS, the five-membered heterocyclic ring and the N—(C=O)—C plane of the acetamide group are essentially co-planar, with a dihedral angle of 1.25 (3)°. Inter­molecular N—H⋯O hydrogen bonds between the acetamide compound and the dimethyl sulfoxide mol­ecules stabilize the crystal structure. The two dimethyl sulfoxide mol­ecules are each disordered over two positions with occupancy ratios of 0.605 (2):0.395 (2) and 0.8629 (18):0.1371 (18). International Union of Crystallography 2011-12-23 /pmc/articles/PMC3254557/ /pubmed/22259506 http://dx.doi.org/10.1107/S1600536811054298 Text en © Kang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kang, Sung Kwon
Cho, Nam Sook
Jang, Siyoung
N-(5-Sulfanyl­idene-4,5-dihydro-1,3,4-thia­diazol-2-yl)acetamide dimethyl sulfoxide disolvate
title N-(5-Sulfanyl­idene-4,5-dihydro-1,3,4-thia­diazol-2-yl)acetamide dimethyl sulfoxide disolvate
title_full N-(5-Sulfanyl­idene-4,5-dihydro-1,3,4-thia­diazol-2-yl)acetamide dimethyl sulfoxide disolvate
title_fullStr N-(5-Sulfanyl­idene-4,5-dihydro-1,3,4-thia­diazol-2-yl)acetamide dimethyl sulfoxide disolvate
title_full_unstemmed N-(5-Sulfanyl­idene-4,5-dihydro-1,3,4-thia­diazol-2-yl)acetamide dimethyl sulfoxide disolvate
title_short N-(5-Sulfanyl­idene-4,5-dihydro-1,3,4-thia­diazol-2-yl)acetamide dimethyl sulfoxide disolvate
title_sort n-(5-sulfanyl­idene-4,5-dihydro-1,3,4-thia­diazol-2-yl)acetamide dimethyl sulfoxide disolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254557/
https://www.ncbi.nlm.nih.gov/pubmed/22259506
http://dx.doi.org/10.1107/S1600536811054298
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