Methyl­ammonium tetra­fluoridoborate 18-crown-6 clathrate

In the title compound, CH(3)NH(3) (+)·BF(4) (−)·C(12)H(24)O(6), the methyl­ammonium cation makes three N—H⋯O hydrogen bonds to the 18-crown-6 mol­ecule. The –NH(3) (+) and –CH(3) groups of the cation adopt a staggered conformation. The F atoms of the tetra­fluoridoborate anion are disordered over tw...

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Detalles Bibliográficos
Autor principal: Jin, Yu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254558/
https://www.ncbi.nlm.nih.gov/pubmed/22259507
http://dx.doi.org/10.1107/S1600536811054432
Descripción
Sumario:In the title compound, CH(3)NH(3) (+)·BF(4) (−)·C(12)H(24)O(6), the methyl­ammonium cation makes three N—H⋯O hydrogen bonds to the 18-crown-6 mol­ecule. The –NH(3) (+) and –CH(3) groups of the cation adopt a staggered conformation. The F atoms of the tetra­fluoridoborate anion are disordered over two sets of sites in a 0.519 (11):0.481 (11) ratio. Weak C—H⋯F inter­actions occur in the crystal, which possibly correlate with the anion disorder.

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