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Methylammonium tetrafluoridoborate 18-crown-6 clathrate
In the title compound, CH(3)NH(3) (+)·BF(4) (−)·C(12)H(24)O(6), the methylammonium cation makes three N—H⋯O hydrogen bonds to the 18-crown-6 molecule. The –NH(3) (+) and –CH(3) groups of the cation adopt a staggered conformation. The F atoms of the tetrafluoridoborate anion are disordered over tw...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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International Union of Crystallography
2011
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254558/ https://www.ncbi.nlm.nih.gov/pubmed/22259507 http://dx.doi.org/10.1107/S1600536811054432 |
| _version_ | 1782220881377886208 |
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| author | Jin, Yu |
| author_facet | Jin, Yu |
| author_sort | Jin, Yu |
| collection | PubMed |
| description | In the title compound, CH(3)NH(3) (+)·BF(4) (−)·C(12)H(24)O(6), the methylammonium cation makes three N—H⋯O hydrogen bonds to the 18-crown-6 molecule. The –NH(3) (+) and –CH(3) groups of the cation adopt a staggered conformation. The F atoms of the tetrafluoridoborate anion are disordered over two sets of sites in a 0.519 (11):0.481 (11) ratio. Weak C—H⋯F interactions occur in the crystal, which possibly correlate with the anion disorder. |
| format | Online Article Text |
| id | pubmed-3254558 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32545582012-01-18 Methylammonium tetrafluoridoborate 18-crown-6 clathrate Jin, Yu Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, CH(3)NH(3) (+)·BF(4) (−)·C(12)H(24)O(6), the methylammonium cation makes three N—H⋯O hydrogen bonds to the 18-crown-6 molecule. The –NH(3) (+) and –CH(3) groups of the cation adopt a staggered conformation. The F atoms of the tetrafluoridoborate anion are disordered over two sets of sites in a 0.519 (11):0.481 (11) ratio. Weak C—H⋯F interactions occur in the crystal, which possibly correlate with the anion disorder. International Union of Crystallography 2011-12-23 /pmc/articles/PMC3254558/ /pubmed/22259507 http://dx.doi.org/10.1107/S1600536811054432 Text en © Yu Jin 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Jin, Yu Methylammonium tetrafluoridoborate 18-crown-6 clathrate |
| title | Methylammonium tetrafluoridoborate 18-crown-6 clathrate |
| title_full | Methylammonium tetrafluoridoborate 18-crown-6 clathrate |
| title_fullStr | Methylammonium tetrafluoridoborate 18-crown-6 clathrate |
| title_full_unstemmed | Methylammonium tetrafluoridoborate 18-crown-6 clathrate |
| title_short | Methylammonium tetrafluoridoborate 18-crown-6 clathrate |
| title_sort | methylammonium tetrafluoridoborate 18-crown-6 clathrate |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254558/ https://www.ncbi.nlm.nih.gov/pubmed/22259507 http://dx.doi.org/10.1107/S1600536811054432 |
| work_keys_str_mv | AT jinyu methylammoniumtetrafluoridoborate18crown6clathrate |