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Diethyl 2-(triphenyl­meth­yl)malonate

In the title compound, C(26)H(26)O(4), steric crowding of the Ph(3)C– group with the –CH(CO(2)Et)(2) unit leads to a long C—C bond [1.585 (2) Å]. One of the two ethyl groups is disordered over two sites in a 60:40 ratio.

Detalles Bibliográficos
Autores principales: Yuan, Xian-You, Zhang, Min, Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3257068/
https://www.ncbi.nlm.nih.gov/pubmed/22247714
http://dx.doi.org/10.1107/S1600536808018163
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author Yuan, Xian-You
Zhang, Min
Ng, Seik Weng
author_facet Yuan, Xian-You
Zhang, Min
Ng, Seik Weng
author_sort Yuan, Xian-You
collection PubMed
description In the title compound, C(26)H(26)O(4), steric crowding of the Ph(3)C– group with the –CH(CO(2)Et)(2) unit leads to a long C—C bond [1.585 (2) Å]. One of the two ethyl groups is disordered over two sites in a 60:40 ratio.
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spelling pubmed-32570682012-01-13 Diethyl 2-(triphenyl­meth­yl)malonate Yuan, Xian-You Zhang, Min Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(26)H(26)O(4), steric crowding of the Ph(3)C– group with the –CH(CO(2)Et)(2) unit leads to a long C—C bond [1.585 (2) Å]. One of the two ethyl groups is disordered over two sites in a 60:40 ratio. International Union of Crystallography 2008-06-21 /pmc/articles/PMC3257068/ /pubmed/22247714 http://dx.doi.org/10.1107/S1600536808018163 Text en © Yuan et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Yuan, Xian-You
Zhang, Min
Ng, Seik Weng
Diethyl 2-(triphenyl­meth­yl)malonate
title Diethyl 2-(triphenyl­meth­yl)malonate
title_full Diethyl 2-(triphenyl­meth­yl)malonate
title_fullStr Diethyl 2-(triphenyl­meth­yl)malonate
title_full_unstemmed Diethyl 2-(triphenyl­meth­yl)malonate
title_short Diethyl 2-(triphenyl­meth­yl)malonate
title_sort diethyl 2-(triphenyl­meth­yl)malonate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3257068/
https://www.ncbi.nlm.nih.gov/pubmed/22247714
http://dx.doi.org/10.1107/S1600536808018163
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