(1-Naphthyl­imino­meth­yl)ferrocene

In the title mol­ecule, [Fe(C(5)H(5))(C(16)H(12)N)], the cyclo­penta­dienyl rings are approximately eclipsed and the inter­planar angle is 0.8 (7)°. The Fe atom is slightly closer to the substituted cyclo­penta­dienyl ring, with an Fe⋯centroid distance of 1.639 (2) Å, compared with 1.645 (2) Å for t...

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Detalles Bibliográficos
Autor principal: Zang, Yunbo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3257069/
https://www.ncbi.nlm.nih.gov/pubmed/22247715
http://dx.doi.org/10.1107/S1600536808026330
Descripción
Sumario:In the title mol­ecule, [Fe(C(5)H(5))(C(16)H(12)N)], the cyclo­penta­dienyl rings are approximately eclipsed and the inter­planar angle is 0.8 (7)°. The Fe atom is slightly closer to the substituted cyclo­penta­dienyl ring, with an Fe⋯centroid distance of 1.639 (2) Å, compared with 1.645 (2) Å for the unsubstituted ring. The C=N double bond is essentially coplanar with the substituted cyclo­penta­dienyl ring with a deviation of 10.3 (1)°. The angle formed by the C=N double bond and the naphthal­ene ring system is 47.1 (1)°. The C—N=C—C torsion angle is 177.32 (5)°.

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