(1-Naphthyl­imino­meth­yl)ferrocene

In the title mol­ecule, [Fe(C(5)H(5))(C(16)H(12)N)], the cyclo­penta­dienyl rings are approximately eclipsed and the inter­planar angle is 0.8 (7)°. The Fe atom is slightly closer to the substituted cyclo­penta­dienyl ring, with an Fe⋯centroid distance of 1.639 (2) Å, compared with 1.645 (2) Å for t...

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Detalles Bibliográficos
Autor principal: Zang, Yunbo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3257069/
https://www.ncbi.nlm.nih.gov/pubmed/22247715
http://dx.doi.org/10.1107/S1600536808026330
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author Zang, Yunbo
author_facet Zang, Yunbo
author_sort Zang, Yunbo
collection PubMed
description In the title mol­ecule, [Fe(C(5)H(5))(C(16)H(12)N)], the cyclo­penta­dienyl rings are approximately eclipsed and the inter­planar angle is 0.8 (7)°. The Fe atom is slightly closer to the substituted cyclo­penta­dienyl ring, with an Fe⋯centroid distance of 1.639 (2) Å, compared with 1.645 (2) Å for the unsubstituted ring. The C=N double bond is essentially coplanar with the substituted cyclo­penta­dienyl ring with a deviation of 10.3 (1)°. The angle formed by the C=N double bond and the naphthal­ene ring system is 47.1 (1)°. The C—N=C—C torsion angle is 177.32 (5)°.
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spelling pubmed-32570692012-01-13 (1-Naphthyl­imino­meth­yl)ferrocene Zang, Yunbo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title mol­ecule, [Fe(C(5)H(5))(C(16)H(12)N)], the cyclo­penta­dienyl rings are approximately eclipsed and the inter­planar angle is 0.8 (7)°. The Fe atom is slightly closer to the substituted cyclo­penta­dienyl ring, with an Fe⋯centroid distance of 1.639 (2) Å, compared with 1.645 (2) Å for the unsubstituted ring. The C=N double bond is essentially coplanar with the substituted cyclo­penta­dienyl ring with a deviation of 10.3 (1)°. The angle formed by the C=N double bond and the naphthal­ene ring system is 47.1 (1)°. The C—N=C—C torsion angle is 177.32 (5)°. International Union of Crystallography 2008-08-20 /pmc/articles/PMC3257069/ /pubmed/22247715 http://dx.doi.org/10.1107/S1600536808026330 Text en © Yunbo Zang 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zang, Yunbo
(1-Naphthyl­imino­meth­yl)ferrocene
title (1-Naphthyl­imino­meth­yl)ferrocene
title_full (1-Naphthyl­imino­meth­yl)ferrocene
title_fullStr (1-Naphthyl­imino­meth­yl)ferrocene
title_full_unstemmed (1-Naphthyl­imino­meth­yl)ferrocene
title_short (1-Naphthyl­imino­meth­yl)ferrocene
title_sort (1-naphthyl­imino­meth­yl)ferrocene
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3257069/
https://www.ncbi.nlm.nih.gov/pubmed/22247715
http://dx.doi.org/10.1107/S1600536808026330
work_keys_str_mv AT zangyunbo 1naphthyliminomethylferrocene

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