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H(2) Sensing Response of Flame-Spray-Made Ru/SnO(2) Thick Films Fabricated from Spin-Coated Nanoparticles

High specific surface area (SSA(BET): 141.6 m(2)/g) SnO(2) nanoparticles doped with 0.2–3 wt% Ru were successfully produced in a single step by flame spray pyrolysis (FSP). The phase and crystallite size were analyzed by XRD. The specific surface area (SSA(BET)) of the nanoparticles was measured by...

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Autores principales: Liewhiran, Chaikarn, Tamaekong, Nittaya, Wisitsoraat, Anurat, Phanichphant, Sukon
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Molecular Diversity Preservation International (MDPI) 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3260626/
https://www.ncbi.nlm.nih.gov/pubmed/22291549
http://dx.doi.org/10.3390/s91108996
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author Liewhiran, Chaikarn
Tamaekong, Nittaya
Wisitsoraat, Anurat
Phanichphant, Sukon
author_facet Liewhiran, Chaikarn
Tamaekong, Nittaya
Wisitsoraat, Anurat
Phanichphant, Sukon
author_sort Liewhiran, Chaikarn
collection PubMed
description High specific surface area (SSA(BET): 141.6 m(2)/g) SnO(2) nanoparticles doped with 0.2–3 wt% Ru were successfully produced in a single step by flame spray pyrolysis (FSP). The phase and crystallite size were analyzed by XRD. The specific surface area (SSA(BET)) of the nanoparticles was measured by nitrogen adsorption (BET analysis). As the Ru concentration increased, the SSA(BET) was found to linearly decrease, while the average BET-equivalent particle diameter (d(BET)) increased. FSP yielded small Ru particles attached to the surface of the supporting SnO(2) nanoparticles, indicating a high SSA(BET). The morphology and accurate size of the primary particles were further investigated by TEM. The crystallite sizes of the spherical, hexagonal, and rectangular SnO(2) particles were in the range of 3–10 nm. SnO(2) nanorods were found to range from 3–5 nm in width and 5–20 nm in length. Sensing films were prepared by the spin coating technique. The gas sensing of H(2) (500–10,000 ppm) was studied at the operating temperatures ranging from 200–350 °C in presence of dry air. After the sensing tests, the morphology and the cross-section of sensing film were analyzed by SEM and EDS analyses. The 0.2%Ru-dispersed on SnO(2) sensing film showed the highest sensitivity and a very fast response time (6 s) compared to a pure SnO(2) sensing film, with a highest H(2) concentration of 1 vol% at 350 °C and a low H(2) detection limit of 500 ppm at 200 °C.
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spelling pubmed-32606262012-01-30 H(2) Sensing Response of Flame-Spray-Made Ru/SnO(2) Thick Films Fabricated from Spin-Coated Nanoparticles Liewhiran, Chaikarn Tamaekong, Nittaya Wisitsoraat, Anurat Phanichphant, Sukon Sensors (Basel) Article High specific surface area (SSA(BET): 141.6 m(2)/g) SnO(2) nanoparticles doped with 0.2–3 wt% Ru were successfully produced in a single step by flame spray pyrolysis (FSP). The phase and crystallite size were analyzed by XRD. The specific surface area (SSA(BET)) of the nanoparticles was measured by nitrogen adsorption (BET analysis). As the Ru concentration increased, the SSA(BET) was found to linearly decrease, while the average BET-equivalent particle diameter (d(BET)) increased. FSP yielded small Ru particles attached to the surface of the supporting SnO(2) nanoparticles, indicating a high SSA(BET). The morphology and accurate size of the primary particles were further investigated by TEM. The crystallite sizes of the spherical, hexagonal, and rectangular SnO(2) particles were in the range of 3–10 nm. SnO(2) nanorods were found to range from 3–5 nm in width and 5–20 nm in length. Sensing films were prepared by the spin coating technique. The gas sensing of H(2) (500–10,000 ppm) was studied at the operating temperatures ranging from 200–350 °C in presence of dry air. After the sensing tests, the morphology and the cross-section of sensing film were analyzed by SEM and EDS analyses. The 0.2%Ru-dispersed on SnO(2) sensing film showed the highest sensitivity and a very fast response time (6 s) compared to a pure SnO(2) sensing film, with a highest H(2) concentration of 1 vol% at 350 °C and a low H(2) detection limit of 500 ppm at 200 °C. Molecular Diversity Preservation International (MDPI) 2009-11-11 /pmc/articles/PMC3260626/ /pubmed/22291549 http://dx.doi.org/10.3390/s91108996 Text en © 2009 by the authors; licensee Molecular Diversity Preservation International, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Article
Liewhiran, Chaikarn
Tamaekong, Nittaya
Wisitsoraat, Anurat
Phanichphant, Sukon
H(2) Sensing Response of Flame-Spray-Made Ru/SnO(2) Thick Films Fabricated from Spin-Coated Nanoparticles
title H(2) Sensing Response of Flame-Spray-Made Ru/SnO(2) Thick Films Fabricated from Spin-Coated Nanoparticles
title_full H(2) Sensing Response of Flame-Spray-Made Ru/SnO(2) Thick Films Fabricated from Spin-Coated Nanoparticles
title_fullStr H(2) Sensing Response of Flame-Spray-Made Ru/SnO(2) Thick Films Fabricated from Spin-Coated Nanoparticles
title_full_unstemmed H(2) Sensing Response of Flame-Spray-Made Ru/SnO(2) Thick Films Fabricated from Spin-Coated Nanoparticles
title_short H(2) Sensing Response of Flame-Spray-Made Ru/SnO(2) Thick Films Fabricated from Spin-Coated Nanoparticles
title_sort h(2) sensing response of flame-spray-made ru/sno(2) thick films fabricated from spin-coated nanoparticles
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3260626/
https://www.ncbi.nlm.nih.gov/pubmed/22291549
http://dx.doi.org/10.3390/s91108996
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