A cobalt complex of a microbial arene oxidation product

We report the first synthesis of a cobalt Cp diene complex wherein the diene is derived by microbial dearomatising dihydroxylation of an aromatic ring. The complex has been characterised crystallographically and its structure is compared to that of an uncomplexed diene precursor.

Detalles Bibliográficos
Autores principales: van der Waals, Dominic, Pugh, Thomas, Khan, Monika Ali, Stewart, Alan JW, Johnson, Andrew L, Lewis, Simon E
Formato: Online Artículo Texto
Lenguaje:English
Publicado: BioMed Central 2011
Materias:
Research Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3268747/
https://www.ncbi.nlm.nih.gov/pubmed/22152033
http://dx.doi.org/10.1186/1752-153X-5-80
Descripción
Sumario:We report the first synthesis of a cobalt Cp diene complex wherein the diene is derived by microbial dearomatising dihydroxylation of an aromatic ring. The complex has been characterised crystallographically and its structure is compared to that of an uncomplexed diene precursor.

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