Lithium europium(III) molybdate(VI), Li(3.5)Eu(1.5)(MoO(4))(4)

The title compound, Li(3.5)Eu(1.5)(MoO(4))(4), was prepared by solid-state reactions. The fundamental building units of the structure are LiO(4) polyhedra (site symmetry [Image: see text]), distorted LiO(6) polyhedra and MoO(4) tetra­hedra, which are further inter­connected via corner-sharing O atom...

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Detalles Bibliográficos
Autores principales: Zhao, Dan, Zhu, Jing, Liang, Peng, Chang, Huan, He, Rong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274837/
https://www.ncbi.nlm.nih.gov/pubmed/22346790
http://dx.doi.org/10.1107/S1600536812000268
Descripción
Sumario:The title compound, Li(3.5)Eu(1.5)(MoO(4))(4), was prepared by solid-state reactions. The fundamental building units of the structure are LiO(4) polyhedra (site symmetry [Image: see text]), distorted LiO(6) polyhedra and MoO(4) tetra­hedra, which are further inter­connected via corner-sharing O atoms. One site is occupied by both Li and Eu atoms in a substituent disordered manner (0.25:0.75), and the Li/Eu atoms are coordinated by eight O atoms in a distorted square-antiprismatic manner.

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