Cargando…
Lithium europium(III) molybdate(VI), Li(3.5)Eu(1.5)(MoO(4))(4)
The title compound, Li(3.5)Eu(1.5)(MoO(4))(4), was prepared by solid-state reactions. The fundamental building units of the structure are LiO(4) polyhedra (site symmetry [Image: see text]), distorted LiO(6) polyhedra and MoO(4) tetrahedra, which are further interconnected via corner-sharing O atom...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274837/ https://www.ncbi.nlm.nih.gov/pubmed/22346790 http://dx.doi.org/10.1107/S1600536812000268 |
_version_ | 1782223116334792704 |
---|---|
author | Zhao, Dan Zhu, Jing Liang, Peng Chang, Huan He, Rong |
author_facet | Zhao, Dan Zhu, Jing Liang, Peng Chang, Huan He, Rong |
author_sort | Zhao, Dan |
collection | PubMed |
description | The title compound, Li(3.5)Eu(1.5)(MoO(4))(4), was prepared by solid-state reactions. The fundamental building units of the structure are LiO(4) polyhedra (site symmetry [Image: see text]), distorted LiO(6) polyhedra and MoO(4) tetrahedra, which are further interconnected via corner-sharing O atoms. One site is occupied by both Li and Eu atoms in a substituent disordered manner (0.25:0.75), and the Li/Eu atoms are coordinated by eight O atoms in a distorted square-antiprismatic manner. |
format | Online Article Text |
id | pubmed-3274837 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32748372012-02-15 Lithium europium(III) molybdate(VI), Li(3.5)Eu(1.5)(MoO(4))(4) Zhao, Dan Zhu, Jing Liang, Peng Chang, Huan He, Rong Acta Crystallogr Sect E Struct Rep Online Inorganic Papers The title compound, Li(3.5)Eu(1.5)(MoO(4))(4), was prepared by solid-state reactions. The fundamental building units of the structure are LiO(4) polyhedra (site symmetry [Image: see text]), distorted LiO(6) polyhedra and MoO(4) tetrahedra, which are further interconnected via corner-sharing O atoms. One site is occupied by both Li and Eu atoms in a substituent disordered manner (0.25:0.75), and the Li/Eu atoms are coordinated by eight O atoms in a distorted square-antiprismatic manner. International Union of Crystallography 2012-01-11 /pmc/articles/PMC3274837/ /pubmed/22346790 http://dx.doi.org/10.1107/S1600536812000268 Text en © Zhao et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Inorganic Papers Zhao, Dan Zhu, Jing Liang, Peng Chang, Huan He, Rong Lithium europium(III) molybdate(VI), Li(3.5)Eu(1.5)(MoO(4))(4) |
title | Lithium europium(III) molybdate(VI), Li(3.5)Eu(1.5)(MoO(4))(4)
|
title_full | Lithium europium(III) molybdate(VI), Li(3.5)Eu(1.5)(MoO(4))(4)
|
title_fullStr | Lithium europium(III) molybdate(VI), Li(3.5)Eu(1.5)(MoO(4))(4)
|
title_full_unstemmed | Lithium europium(III) molybdate(VI), Li(3.5)Eu(1.5)(MoO(4))(4)
|
title_short | Lithium europium(III) molybdate(VI), Li(3.5)Eu(1.5)(MoO(4))(4)
|
title_sort | lithium europium(iii) molybdate(vi), li(3.5)eu(1.5)(moo(4))(4) |
topic | Inorganic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274837/ https://www.ncbi.nlm.nih.gov/pubmed/22346790 http://dx.doi.org/10.1107/S1600536812000268 |
work_keys_str_mv | AT zhaodan lithiumeuropiumiiimolybdatevili35eu15moo44 AT zhujing lithiumeuropiumiiimolybdatevili35eu15moo44 AT liangpeng lithiumeuropiumiiimolybdatevili35eu15moo44 AT changhuan lithiumeuropiumiiimolybdatevili35eu15moo44 AT herong lithiumeuropiumiiimolybdatevili35eu15moo44 |