Bis(μ-2-carb­oxy-5-nitro­benzoato-κ(2) O (1):O (1))bis­[(2,2′-bipyridine-κ(2) N:N′)chloridocopper(II)] dihydrate

The asymmetric unit of the title complex, [Cu(2)(C(8)H(4)NO(6))(2)Cl(2)(C(10)H(8)N(2))(2)]·2H(2)O, contains two half binuclear complex molecules and two solvent water molecules; the complete complex molecule is generated by the application of a centre of inversion in each case. Each independent Cu(I...

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Detalles Bibliográficos
Autor principal: Wang, Hui
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274844/
https://www.ncbi.nlm.nih.gov/pubmed/22346893
http://dx.doi.org/10.1107/S1600536811046782
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author Wang, Hui
author_facet Wang, Hui
author_sort Wang, Hui
collection PubMed
description The asymmetric unit of the title complex, [Cu(2)(C(8)H(4)NO(6))(2)Cl(2)(C(10)H(8)N(2))(2)]·2H(2)O, contains two half binuclear complex molecules and two solvent water molecules; the complete complex molecule is generated by the application of a centre of inversion in each case. Each independent Cu(II) cation is penta-coordinated within a distorted square-pyramidal environment defined by a two μ(2)-O atoms (derived from two 2-carboxy-5-nitrobenzoato anions), two N atoms (bipyridine ligand) and one Cl. Binuclear species are assembled into a two-dimensional supramolecular architecture parallel to (01[Image: see text]) by O—H⋯O and O—H⋯Cl hydrogen bonds.
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spelling pubmed-32748442012-02-15 Bis(μ-2-carb­oxy-5-nitro­benzoato-κ(2) O (1):O (1))bis­[(2,2′-bipyridine-κ(2) N:N′)chloridocopper(II)] dihydrate Wang, Hui Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title complex, [Cu(2)(C(8)H(4)NO(6))(2)Cl(2)(C(10)H(8)N(2))(2)]·2H(2)O, contains two half binuclear complex molecules and two solvent water molecules; the complete complex molecule is generated by the application of a centre of inversion in each case. Each independent Cu(II) cation is penta-coordinated within a distorted square-pyramidal environment defined by a two μ(2)-O atoms (derived from two 2-carboxy-5-nitrobenzoato anions), two N atoms (bipyridine ligand) and one Cl. Binuclear species are assembled into a two-dimensional supramolecular architecture parallel to (01[Image: see text]) by O—H⋯O and O—H⋯Cl hydrogen bonds. International Union of Crystallography 2012-01-07 /pmc/articles/PMC3274844/ /pubmed/22346893 http://dx.doi.org/10.1107/S1600536811046782 Text en © Hui Wang 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Hui
Bis(μ-2-carb­oxy-5-nitro­benzoato-κ(2) O (1):O (1))bis­[(2,2′-bipyridine-κ(2) N:N′)chloridocopper(II)] dihydrate
title Bis(μ-2-carb­oxy-5-nitro­benzoato-κ(2) O (1):O (1))bis­[(2,2′-bipyridine-κ(2) N:N′)chloridocopper(II)] dihydrate
title_full Bis(μ-2-carb­oxy-5-nitro­benzoato-κ(2) O (1):O (1))bis­[(2,2′-bipyridine-κ(2) N:N′)chloridocopper(II)] dihydrate
title_fullStr Bis(μ-2-carb­oxy-5-nitro­benzoato-κ(2) O (1):O (1))bis­[(2,2′-bipyridine-κ(2) N:N′)chloridocopper(II)] dihydrate
title_full_unstemmed Bis(μ-2-carb­oxy-5-nitro­benzoato-κ(2) O (1):O (1))bis­[(2,2′-bipyridine-κ(2) N:N′)chloridocopper(II)] dihydrate
title_short Bis(μ-2-carb­oxy-5-nitro­benzoato-κ(2) O (1):O (1))bis­[(2,2′-bipyridine-κ(2) N:N′)chloridocopper(II)] dihydrate
title_sort bis(μ-2-carb­oxy-5-nitro­benzoato-κ(2) o (1):o (1))bis­[(2,2′-bipyridine-κ(2) n:n′)chloridocopper(ii)] dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274844/
https://www.ncbi.nlm.nih.gov/pubmed/22346893
http://dx.doi.org/10.1107/S1600536811046782
work_keys_str_mv AT wanghui bism2carboxy5nitrobenzoatok2o1o1bis22bipyridinek2nnchloridocopperiidihydrate

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