Aqua­[tris­(2-{5-[(4-methyl­phenyl)diazen­yl]-2-oxidobenzyl­idene­amino}­eth­yl)amine]­samarium(III) acetonitrile monosolvate

In the title compound, [Sm(C(48)H(45)N(10)O(3))(H(2)O)]·CH(3)CN, the Sm(III) ion is coordinated by the hepta­dentate tris­(2-{5-[(4-methyl­pheny)diazen­yl]-2-oxidobenzyl­idene­amino}­eth­yl)amine trianionic ligand and a water mol­ecule. The resulting SmN(4)O(4) coordination polyhedron is a distorted...

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Detalles Bibliográficos
Autores principales: Salehzadeh, Sadegh, Mahdavian, Mahsa, Khalaj, Mehdi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3274845/
https://www.ncbi.nlm.nih.gov/pubmed/22346894
http://dx.doi.org/10.1107/S1600536811054961
Descripción
Sumario:In the title compound, [Sm(C(48)H(45)N(10)O(3))(H(2)O)]·CH(3)CN, the Sm(III) ion is coordinated by the hepta­dentate tris­(2-{5-[(4-methyl­pheny)diazen­yl]-2-oxidobenzyl­idene­amino}­eth­yl)amine trianionic ligand and a water mol­ecule. The resulting SmN(4)O(4) coordination polyhedron is a distorted square anti­prism. In the crystal, complex mol­ecules are linked by O—H⋯O hydrogen bonds.

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